Synthesis and properties of polyfluoro(silyl)acetylene nanoparticles by reaction of fluoro(silyl)acetylenes with triethylamine

Fluoro(silyl)acetylenes, which were prepared by reaction of 1,1-difluoroethylene with silyl chlorides, reacted with triethylamine to give dark-brown colored polyfluoro(silyl)acetylene powders in excellent to moderate isolated yields. In contrast, the corresponding nonfluorinated acetylene was unable...

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Veröffentlicht in:	Colloid and polymer science 2013-05, Vol.291 (5), p.1211-1217
Hauptverfasser:	Goto, Yuki, Shiosaki, Masahiro, Hanamoto, Takeshi, Yoshida, Masato, Sawada, Hideo
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetylene Applied sciences Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Chlorides Complex Fluids and Microfluidics Exact sciences and technology Food Science Nanoparticles Nanotechnology and Microengineering Organic polymers Original Contribution Physical Chemistry Physicochemistry of polymers Polymer Sciences Polymers with particular properties Polymethyl methacrylates Preparation, kinetics, thermodynamics, mechanism and catalysts Soft and Granular Matter Solvents Surface chemistry Synthesis Triethylamine
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