Polyimide-b-polysiloxane Copolymers: Synthesis and Properties
This review discusses the synthesis, structure and properties of polyimide- b -polysiloxane copolymers. Polysiloxane modified polyimides has become an important class of materials over the past 20 years because of their ease of processing and interesting properties. Although polyimides are widely us...
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Veröffentlicht in: | Journal of inorganic and organometallic polymers and materials 2013-05, Vol.23 (3), p.477-488 |
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container_title | Journal of inorganic and organometallic polymers and materials |
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creator | Feng, Linqian Iroh, Jude O. |
description | This review discusses the synthesis, structure and properties of polyimide-
b
-polysiloxane copolymers. Polysiloxane modified polyimides has become an important class of materials over the past 20 years because of their ease of processing and interesting properties. Although polyimides are widely used in engineering applications because of their outstanding mechanical properties and thermal stability, their processability, toughness, and adhesion can be significantly enhanced by incorporation of polysiloxanes. The synthesis of polyimide-
b
-polysiloxane copolymers is performed by a one-step copolymerization method or a two-step method, resulting in a wide range structures and thermo-mechanical properties. The initial modulus and thermal stability of polyimide-
b
-linear polysiloxane copolymers can be further improved by copolymerization with ladder-like polysiloxanes which possess outstanding thermal stability and mechanical properties. The study of synthesis and properties of polyimide-
b
-polysiloxane copolymers is essential because it provides a useful insight into the processing-structure–property relationship. |
doi_str_mv | 10.1007/s10904-012-9795-4 |
format | Article |
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b
-polysiloxane copolymers. Polysiloxane modified polyimides has become an important class of materials over the past 20 years because of their ease of processing and interesting properties. Although polyimides are widely used in engineering applications because of their outstanding mechanical properties and thermal stability, their processability, toughness, and adhesion can be significantly enhanced by incorporation of polysiloxanes. The synthesis of polyimide-
b
-polysiloxane copolymers is performed by a one-step copolymerization method or a two-step method, resulting in a wide range structures and thermo-mechanical properties. The initial modulus and thermal stability of polyimide-
b
-linear polysiloxane copolymers can be further improved by copolymerization with ladder-like polysiloxanes which possess outstanding thermal stability and mechanical properties. The study of synthesis and properties of polyimide-
b
-polysiloxane copolymers is essential because it provides a useful insight into the processing-structure–property relationship.</description><identifier>ISSN: 1574-1443</identifier><identifier>EISSN: 1574-1451</identifier><identifier>DOI: 10.1007/s10904-012-9795-4</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Chemistry ; Chemistry and Materials Science ; Copolymerization ; Copolymers ; Inorganic Chemistry ; Mechanical properties ; Organic Chemistry ; Organometallic polymers ; Polyimide resins ; Polymer Sciences ; Polysiloxanes ; Review ; Synthesis ; Thermal stability</subject><ispartof>Journal of inorganic and organometallic polymers and materials, 2013-05, Vol.23 (3), p.477-488</ispartof><rights>Springer Science+Business Media New York 2012</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c321t-c39d013a46cde02ce9f302d8e52f6028ddb1f29759aeab7ba68fe9f8c77d42313</citedby><cites>FETCH-LOGICAL-c321t-c39d013a46cde02ce9f302d8e52f6028ddb1f29759aeab7ba68fe9f8c77d42313</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10904-012-9795-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10904-012-9795-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Feng, Linqian</creatorcontrib><creatorcontrib>Iroh, Jude O.</creatorcontrib><title>Polyimide-b-polysiloxane Copolymers: Synthesis and Properties</title><title>Journal of inorganic and organometallic polymers and materials</title><addtitle>J Inorg Organomet Polym</addtitle><description>This review discusses the synthesis, structure and properties of polyimide-
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-polysiloxane copolymers. Polysiloxane modified polyimides has become an important class of materials over the past 20 years because of their ease of processing and interesting properties. Although polyimides are widely used in engineering applications because of their outstanding mechanical properties and thermal stability, their processability, toughness, and adhesion can be significantly enhanced by incorporation of polysiloxanes. The synthesis of polyimide-
b
-polysiloxane copolymers is performed by a one-step copolymerization method or a two-step method, resulting in a wide range structures and thermo-mechanical properties. The initial modulus and thermal stability of polyimide-
b
-linear polysiloxane copolymers can be further improved by copolymerization with ladder-like polysiloxanes which possess outstanding thermal stability and mechanical properties. The study of synthesis and properties of polyimide-
b
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b
-polysiloxane copolymers is performed by a one-step copolymerization method or a two-step method, resulting in a wide range structures and thermo-mechanical properties. The initial modulus and thermal stability of polyimide-
b
-linear polysiloxane copolymers can be further improved by copolymerization with ladder-like polysiloxanes which possess outstanding thermal stability and mechanical properties. The study of synthesis and properties of polyimide-
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subjects | Chemistry Chemistry and Materials Science Copolymerization Copolymers Inorganic Chemistry Mechanical properties Organic Chemistry Organometallic polymers Polyimide resins Polymer Sciences Polysiloxanes Review Synthesis Thermal stability |
title | Polyimide-b-polysiloxane Copolymers: Synthesis and Properties |
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