Polyimide-b-polysiloxane Copolymers: Synthesis and Properties

This review discusses the synthesis, structure and properties of polyimide- b -polysiloxane copolymers. Polysiloxane modified polyimides has become an important class of materials over the past 20 years because of their ease of processing and interesting properties. Although polyimides are widely us...

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Veröffentlicht in:Journal of inorganic and organometallic polymers and materials 2013-05, Vol.23 (3), p.477-488
Hauptverfasser: Feng, Linqian, Iroh, Jude O.
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Iroh, Jude O.
description This review discusses the synthesis, structure and properties of polyimide- b -polysiloxane copolymers. Polysiloxane modified polyimides has become an important class of materials over the past 20 years because of their ease of processing and interesting properties. Although polyimides are widely used in engineering applications because of their outstanding mechanical properties and thermal stability, their processability, toughness, and adhesion can be significantly enhanced by incorporation of polysiloxanes. The synthesis of polyimide- b -polysiloxane copolymers is performed by a one-step copolymerization method or a two-step method, resulting in a wide range structures and thermo-mechanical properties. The initial modulus and thermal stability of polyimide- b -linear polysiloxane copolymers can be further improved by copolymerization with ladder-like polysiloxanes which possess outstanding thermal stability and mechanical properties. The study of synthesis and properties of polyimide- b -polysiloxane copolymers is essential because it provides a useful insight into the processing-structure–property relationship.
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subjects Chemistry
Chemistry and Materials Science
Copolymerization
Copolymers
Inorganic Chemistry
Mechanical properties
Organic Chemistry
Organometallic polymers
Polyimide resins
Polymer Sciences
Polysiloxanes
Review
Synthesis
Thermal stability
title Polyimide-b-polysiloxane Copolymers: Synthesis and Properties
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