Metallopolymer Films Exhibiting Three-Color Electrochromism in the UV/Vis and Near-IR Region: Remarkable Utility of Trimetallic Clusters Bearing Thienyl Pendants and Their Mixed-Valent Charge Transfer Transitions
Novel oxo-centered, acetate-bridged trinuclear ruthenium clusters functionalized with two pyridine ligands with thienyl substituents, [Ru 3 O(CH 3 COO) 6 (CO)(L1) 2 ] ( 1 ) and [Ru 3 O(CH 3 COO) 6 (CO)(L2) 2 ] ( 2 ), where L1 = 4-(2-thienyl)pyridine and L2 = 4-(2,2′-bithienyl)pyridine, have been syn...
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| Veröffentlicht in: | Journal of inorganic and organometallic polymers and materials 2013, Vol.23 (1), p.136-146 |
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| container_title | Journal of inorganic and organometallic polymers and materials |
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| creator | Matsuse, Rumiko Abe, Masaaki Tomiyasu, Yuki Inatomi, Atsushi Yonemura, Hiroaki Yamada, Sunao Hisaeda, Yoshio |
| description | Novel oxo-centered, acetate-bridged trinuclear ruthenium clusters functionalized with two pyridine ligands with thienyl substituents, [Ru
3
O(CH
3
COO)
6
(CO)(L1)
2
] (
1
) and [Ru
3
O(CH
3
COO)
6
(CO)(L2)
2
] (
2
), where L1 = 4-(2-thienyl)pyridine and L2 = 4-(2,2′-bithienyl)pyridine, have been synthesized and characterized. The molecular structure of
2
has been determined by single-crystal X-ray diffraction. One-electron oxidation of
2
with silver(I) cation has led to the isolation of a CO-dissociated product, [Ru
3
O(CH
3
COO)
6
(H
2
O)(L2)
2
]PF
6
(
3·PF
6
), and subsequent reaction with 4-dimethylaminopyridine (dmap) gave [Ru
3
O(CH
3
COO)
6
(dmap)(L2)
2
]PF
6
(
4·PF
6
). Linear metallopolymers containing the {Ru
3
O(CH
3
COO)
6
} groups have been deposited onto indium-tin oxide surface via oxidative electropolymerization of
2
,
3·PF
6
, and
4·PF
6
. These metallopolymer thin films exhibit three-color electrochromism in the UV/Vis and near-IR region associated with the Ru
3
II,III,III
, Ru
3
III,III,III
, and Ru
3
III,III,IV
oxidation states. |
| doi_str_mv | 10.1007/s10904-012-9758-9 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1429863986</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1429863986</sourcerecordid><originalsourceid>FETCH-LOGICAL-c321t-a39cd40d6fe49b28a0c06d23b8ee98ad9ef69696b24c71e0a63919c92ac6e5d03</originalsourceid><addsrcrecordid>eNp9UU1vEzEQtRBIlMAP4DZHLqb2fmXNDVZpqdQCqtJcLa93NuvitYPtSM3_5AfhdBFHNBrNHOa9mXmPkPecfeSMrS8jZ4JVlPGCinXdUvGCXPB6XVFe1fzlv74qX5M3MT4yVras5hfk9x0mZa0_eHuaMcCVsXOEzdNkepOM28N2Coi089YH2FjUKXg9BT-bOINxkCaEh93lzkRQboBvqAK9uYd73BvvPuU6q_BT9TZPJWNNOoEfYRvM_LzWaOjsMSYMEb5k6LLQoDtZ-IFuUC4tvNsJTYA784QD3SmLLkE3qbDHzKVcHPPlz02-2bv4lrwalY347m9dkYerzbb7Sm-_X990n2-pLgueqCqFHio2NCNWoi9axTRrhqLsW0TRqkHg2IgcfVHpNUemmlJwoUWhdIP1wMoV-bDwHoL_dcSYZJZFo7XKoT9GyatCtBmUc0X4MqqDjzHgKA9ZBBVOkjN5dlAuDsrsoDw7KEXGFAsmHs7KYJCP_hhc_ug_oD-AlKM2</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1429863986</pqid></control><display><type>article</type><title>Metallopolymer Films Exhibiting Three-Color Electrochromism in the UV/Vis and Near-IR Region: Remarkable Utility of Trimetallic Clusters Bearing Thienyl Pendants and Their Mixed-Valent Charge Transfer Transitions</title><source>Springer Online Journals Complete</source><creator>Matsuse, Rumiko ; Abe, Masaaki ; Tomiyasu, Yuki ; Inatomi, Atsushi ; Yonemura, Hiroaki ; Yamada, Sunao ; Hisaeda, Yoshio</creator><creatorcontrib>Matsuse, Rumiko ; Abe, Masaaki ; Tomiyasu, Yuki ; Inatomi, Atsushi ; Yonemura, Hiroaki ; Yamada, Sunao ; Hisaeda, Yoshio</creatorcontrib><description>Novel oxo-centered, acetate-bridged trinuclear ruthenium clusters functionalized with two pyridine ligands with thienyl substituents, [Ru
3
O(CH
3
COO)
6
(CO)(L1)
2
] (
1
) and [Ru
3
O(CH
3
COO)
6
(CO)(L2)
2
] (
2
), where L1 = 4-(2-thienyl)pyridine and L2 = 4-(2,2′-bithienyl)pyridine, have been synthesized and characterized. The molecular structure of
2
has been determined by single-crystal X-ray diffraction. One-electron oxidation of
2
with silver(I) cation has led to the isolation of a CO-dissociated product, [Ru
3
O(CH
3
COO)
6
(H
2
O)(L2)
2
]PF
6
(
3·PF
6
), and subsequent reaction with 4-dimethylaminopyridine (dmap) gave [Ru
3
O(CH
3
COO)
6
(dmap)(L2)
2
]PF
6
(
4·PF
6
). Linear metallopolymers containing the {Ru
3
O(CH
3
COO)
6
} groups have been deposited onto indium-tin oxide surface via oxidative electropolymerization of
2
,
3·PF
6
, and
4·PF
6
. These metallopolymer thin films exhibit three-color electrochromism in the UV/Vis and near-IR region associated with the Ru
3
II,III,III
, Ru
3
III,III,III
, and Ru
3
III,III,IV
oxidation states.</description><identifier>ISSN: 1574-1443</identifier><identifier>EISSN: 1574-1451</identifier><identifier>DOI: 10.1007/s10904-012-9758-9</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Cations ; Charge transfer ; Chemistry ; Chemistry and Materials Science ; Clusters ; Diffraction ; Electrochromism ; Inorganic Chemistry ; Jewelry ; Molecular structure ; Organic Chemistry ; Polymer Sciences ; Pyridines</subject><ispartof>Journal of inorganic and organometallic polymers and materials, 2013, Vol.23 (1), p.136-146</ispartof><rights>Springer Science+Business Media, LLC 2012</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c321t-a39cd40d6fe49b28a0c06d23b8ee98ad9ef69696b24c71e0a63919c92ac6e5d03</citedby><cites>FETCH-LOGICAL-c321t-a39cd40d6fe49b28a0c06d23b8ee98ad9ef69696b24c71e0a63919c92ac6e5d03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10904-012-9758-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10904-012-9758-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,781,785,27929,27930,41493,42562,51324</link.rule.ids></links><search><creatorcontrib>Matsuse, Rumiko</creatorcontrib><creatorcontrib>Abe, Masaaki</creatorcontrib><creatorcontrib>Tomiyasu, Yuki</creatorcontrib><creatorcontrib>Inatomi, Atsushi</creatorcontrib><creatorcontrib>Yonemura, Hiroaki</creatorcontrib><creatorcontrib>Yamada, Sunao</creatorcontrib><creatorcontrib>Hisaeda, Yoshio</creatorcontrib><title>Metallopolymer Films Exhibiting Three-Color Electrochromism in the UV/Vis and Near-IR Region: Remarkable Utility of Trimetallic Clusters Bearing Thienyl Pendants and Their Mixed-Valent Charge Transfer Transitions</title><title>Journal of inorganic and organometallic polymers and materials</title><addtitle>J Inorg Organomet Polym</addtitle><description>Novel oxo-centered, acetate-bridged trinuclear ruthenium clusters functionalized with two pyridine ligands with thienyl substituents, [Ru
3
O(CH
3
COO)
6
(CO)(L1)
2
] (
1
) and [Ru
3
O(CH
3
COO)
6
(CO)(L2)
2
] (
2
), where L1 = 4-(2-thienyl)pyridine and L2 = 4-(2,2′-bithienyl)pyridine, have been synthesized and characterized. The molecular structure of
2
has been determined by single-crystal X-ray diffraction. One-electron oxidation of
2
with silver(I) cation has led to the isolation of a CO-dissociated product, [Ru
3
O(CH
3
COO)
6
(H
2
O)(L2)
2
]PF
6
(
3·PF
6
), and subsequent reaction with 4-dimethylaminopyridine (dmap) gave [Ru
3
O(CH
3
COO)
6
(dmap)(L2)
2
]PF
6
(
4·PF
6
). Linear metallopolymers containing the {Ru
3
O(CH
3
COO)
6
} groups have been deposited onto indium-tin oxide surface via oxidative electropolymerization of
2
,
3·PF
6
, and
4·PF
6
. These metallopolymer thin films exhibit three-color electrochromism in the UV/Vis and near-IR region associated with the Ru
3
II,III,III
, Ru
3
III,III,III
, and Ru
3
III,III,IV
oxidation states.</description><subject>Cations</subject><subject>Charge transfer</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Clusters</subject><subject>Diffraction</subject><subject>Electrochromism</subject><subject>Inorganic Chemistry</subject><subject>Jewelry</subject><subject>Molecular structure</subject><subject>Organic Chemistry</subject><subject>Polymer Sciences</subject><subject>Pyridines</subject><issn>1574-1443</issn><issn>1574-1451</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp9UU1vEzEQtRBIlMAP4DZHLqb2fmXNDVZpqdQCqtJcLa93NuvitYPtSM3_5AfhdBFHNBrNHOa9mXmPkPecfeSMrS8jZ4JVlPGCinXdUvGCXPB6XVFe1fzlv74qX5M3MT4yVras5hfk9x0mZa0_eHuaMcCVsXOEzdNkepOM28N2Coi089YH2FjUKXg9BT-bOINxkCaEh93lzkRQboBvqAK9uYd73BvvPuU6q_BT9TZPJWNNOoEfYRvM_LzWaOjsMSYMEb5k6LLQoDtZ-IFuUC4tvNsJTYA784QD3SmLLkE3qbDHzKVcHPPlz02-2bv4lrwalY347m9dkYerzbb7Sm-_X990n2-pLgueqCqFHio2NCNWoi9axTRrhqLsW0TRqkHg2IgcfVHpNUemmlJwoUWhdIP1wMoV-bDwHoL_dcSYZJZFo7XKoT9GyatCtBmUc0X4MqqDjzHgKA9ZBBVOkjN5dlAuDsrsoDw7KEXGFAsmHs7KYJCP_hhc_ug_oD-AlKM2</recordid><startdate>2013</startdate><enddate>2013</enddate><creator>Matsuse, Rumiko</creator><creator>Abe, Masaaki</creator><creator>Tomiyasu, Yuki</creator><creator>Inatomi, Atsushi</creator><creator>Yonemura, Hiroaki</creator><creator>Yamada, Sunao</creator><creator>Hisaeda, Yoshio</creator><general>Springer US</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>2013</creationdate><title>Metallopolymer Films Exhibiting Three-Color Electrochromism in the UV/Vis and Near-IR Region: Remarkable Utility of Trimetallic Clusters Bearing Thienyl Pendants and Their Mixed-Valent Charge Transfer Transitions</title><author>Matsuse, Rumiko ; Abe, Masaaki ; Tomiyasu, Yuki ; Inatomi, Atsushi ; Yonemura, Hiroaki ; Yamada, Sunao ; Hisaeda, Yoshio</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c321t-a39cd40d6fe49b28a0c06d23b8ee98ad9ef69696b24c71e0a63919c92ac6e5d03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Cations</topic><topic>Charge transfer</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Clusters</topic><topic>Diffraction</topic><topic>Electrochromism</topic><topic>Inorganic Chemistry</topic><topic>Jewelry</topic><topic>Molecular structure</topic><topic>Organic Chemistry</topic><topic>Polymer Sciences</topic><topic>Pyridines</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Matsuse, Rumiko</creatorcontrib><creatorcontrib>Abe, Masaaki</creatorcontrib><creatorcontrib>Tomiyasu, Yuki</creatorcontrib><creatorcontrib>Inatomi, Atsushi</creatorcontrib><creatorcontrib>Yonemura, Hiroaki</creatorcontrib><creatorcontrib>Yamada, Sunao</creatorcontrib><creatorcontrib>Hisaeda, Yoshio</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Matsuse, Rumiko</au><au>Abe, Masaaki</au><au>Tomiyasu, Yuki</au><au>Inatomi, Atsushi</au><au>Yonemura, Hiroaki</au><au>Yamada, Sunao</au><au>Hisaeda, Yoshio</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Metallopolymer Films Exhibiting Three-Color Electrochromism in the UV/Vis and Near-IR Region: Remarkable Utility of Trimetallic Clusters Bearing Thienyl Pendants and Their Mixed-Valent Charge Transfer Transitions</atitle><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle><stitle>J Inorg Organomet Polym</stitle><date>2013</date><risdate>2013</risdate><volume>23</volume><issue>1</issue><spage>136</spage><epage>146</epage><pages>136-146</pages><issn>1574-1443</issn><eissn>1574-1451</eissn><abstract>Novel oxo-centered, acetate-bridged trinuclear ruthenium clusters functionalized with two pyridine ligands with thienyl substituents, [Ru
3
O(CH
3
COO)
6
(CO)(L1)
2
] (
1
) and [Ru
3
O(CH
3
COO)
6
(CO)(L2)
2
] (
2
), where L1 = 4-(2-thienyl)pyridine and L2 = 4-(2,2′-bithienyl)pyridine, have been synthesized and characterized. The molecular structure of
2
has been determined by single-crystal X-ray diffraction. One-electron oxidation of
2
with silver(I) cation has led to the isolation of a CO-dissociated product, [Ru
3
O(CH
3
COO)
6
(H
2
O)(L2)
2
]PF
6
(
3·PF
6
), and subsequent reaction with 4-dimethylaminopyridine (dmap) gave [Ru
3
O(CH
3
COO)
6
(dmap)(L2)
2
]PF
6
(
4·PF
6
). Linear metallopolymers containing the {Ru
3
O(CH
3
COO)
6
} groups have been deposited onto indium-tin oxide surface via oxidative electropolymerization of
2
,
3·PF
6
, and
4·PF
6
. These metallopolymer thin films exhibit three-color electrochromism in the UV/Vis and near-IR region associated with the Ru
3
II,III,III
, Ru
3
III,III,III
, and Ru
3
III,III,IV
oxidation states.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s10904-012-9758-9</doi><tpages>11</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1574-1443 |
| ispartof | Journal of inorganic and organometallic polymers and materials, 2013, Vol.23 (1), p.136-146 |
| issn | 1574-1443 1574-1451 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1429863986 |
| source | Springer Online Journals Complete |
| subjects | Cations Charge transfer Chemistry Chemistry and Materials Science Clusters Diffraction Electrochromism Inorganic Chemistry Jewelry Molecular structure Organic Chemistry Polymer Sciences Pyridines |
| title | Metallopolymer Films Exhibiting Three-Color Electrochromism in the UV/Vis and Near-IR Region: Remarkable Utility of Trimetallic Clusters Bearing Thienyl Pendants and Their Mixed-Valent Charge Transfer Transitions |
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