Slow Photoelectron Velocity-Map Imaging Spectroscopy of Cold Thiozonide (S3 –)
We report high-resolution anion photoelectron spectra of thiozonide (S3 –) acquired by slow electron velocity-map imaging (SEVI). The ions were cryogenically cooled within an ion trap before photodetachment. We measure an electron affinity of 2.3630(9) eV, resolving discrepancies in previously repor...
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| Veröffentlicht in: | The journal of physical chemistry. A 2013-08, Vol.117 (34), p.8126-8131 |
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| container_end_page | 8131 |
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| container_issue | 34 |
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| container_title | The journal of physical chemistry. A |
| container_volume | 117 |
| creator | Kim, Jongjin B. Hock, Christian Yacovitch, Tara I. Neumark, Daniel M. |
| description | We report high-resolution anion photoelectron spectra of thiozonide (S3 –) acquired by slow electron velocity-map imaging (SEVI). The ions were cryogenically cooled within an ion trap before photodetachment. We measure an electron affinity of 2.3630(9) eV, resolving discrepancies in previously reported photoelectron spectra that resulted from the presence of vibrational hot bands. The SEVI spectrum shows well-resolved, extended vibrational progressions in the symmetric stretch and bending modes of S3, yielding accurate frequencies for both. |
| doi_str_mv | 10.1021/jp401083u |
| format | Article |
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The ions were cryogenically cooled within an ion trap before photodetachment. We measure an electron affinity of 2.3630(9) eV, resolving discrepancies in previously reported photoelectron spectra that resulted from the presence of vibrational hot bands. The SEVI spectrum shows well-resolved, extended vibrational progressions in the symmetric stretch and bending modes of S3, yielding accurate frequencies for both.</description><identifier>ISSN: 1089-5639</identifier><identifier>EISSN: 1520-5215</identifier><identifier>DOI: 10.1021/jp401083u</identifier><identifier>PMID: 23461601</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Atomic and molecular physics ; Calculations and mathematical techniques in atomic and molecular physics (excluding electron correlation calculations) ; Coupled cluster theory ; Electronic structure of atoms, molecules and their ions: theory ; Exact sciences and technology ; Ionization potentials, electron affinities, molecular core binding energy ; Molecular properties and interactions with photons ; Photoelectron spectra ; Physics ; Properties of molecules and molecular ions</subject><ispartof>The journal of physical chemistry. 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The SEVI spectrum shows well-resolved, extended vibrational progressions in the symmetric stretch and bending modes of S3, yielding accurate frequencies for both.</description><subject>Atomic and molecular physics</subject><subject>Calculations and mathematical techniques in atomic and molecular physics (excluding electron correlation calculations)</subject><subject>Coupled cluster theory</subject><subject>Electronic structure of atoms, molecules and their ions: theory</subject><subject>Exact sciences and technology</subject><subject>Ionization potentials, electron affinities, molecular core binding energy</subject><subject>Molecular properties and interactions with photons</subject><subject>Photoelectron spectra</subject><subject>Physics</subject><subject>Properties of molecules and molecular ions</subject><issn>1089-5639</issn><issn>1520-5215</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNptkEtOwzAQhi0E4r3gAsgbpHYRGL_ieokqHpVAILWwjWzHgVRJHOJEqKy4AzfkJKS0wIbVjDSf_pn5EDoicEqAkrN5zYHAiHUbaJcICpGgRGz2PYxUJGKmdtBeCHMAIIzybbRDGY9JDGQX3U8L_4rvn33rXeFs2_gKP7rC27xdRLe6xpNSP-XVE57W39Ngfb3APsNjX6R49pz7N1_lqcODKcOf7x_DA7SV6SK4w3XdRw-XF7PxdXRzdzUZn99EmnHRRs4ak7pMiZQJxkECY8YZqZzURNqMCa4yTiQ10giqTOy0lMsnjQEHlGdsHw1WuXXjXzoX2qTMg3VFoSvnu5AQThUlio3iHh2uUNvfHxqXJXWTl7pZJASSpcDkV2DPHq9jO1O69Jf8MdYDJ2tAB6uLrNGVzcMfJyUTAOqP0zYkc981VW_jn4Vfg5KDpw</recordid><startdate>20130829</startdate><enddate>20130829</enddate><creator>Kim, Jongjin B.</creator><creator>Hock, Christian</creator><creator>Yacovitch, Tara I.</creator><creator>Neumark, Daniel M.</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20130829</creationdate><title>Slow Photoelectron Velocity-Map Imaging Spectroscopy of Cold Thiozonide (S3 –)</title><author>Kim, Jongjin B. ; Hock, Christian ; Yacovitch, Tara I. ; Neumark, Daniel M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a345t-ecbbdef95d353407033beb79e7a17cf3549f4172b7b529b6ea774010bb0e024f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Atomic and molecular physics</topic><topic>Calculations and mathematical techniques in atomic and molecular physics (excluding electron correlation calculations)</topic><topic>Coupled cluster theory</topic><topic>Electronic structure of atoms, molecules and their ions: theory</topic><topic>Exact sciences and technology</topic><topic>Ionization potentials, electron affinities, molecular core binding energy</topic><topic>Molecular properties and interactions with photons</topic><topic>Photoelectron spectra</topic><topic>Physics</topic><topic>Properties of molecules and molecular ions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kim, Jongjin B.</creatorcontrib><creatorcontrib>Hock, Christian</creatorcontrib><creatorcontrib>Yacovitch, Tara I.</creatorcontrib><creatorcontrib>Neumark, Daniel M.</creatorcontrib><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>The journal of physical chemistry. A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kim, Jongjin B.</au><au>Hock, Christian</au><au>Yacovitch, Tara I.</au><au>Neumark, Daniel M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Slow Photoelectron Velocity-Map Imaging Spectroscopy of Cold Thiozonide (S3 –)</atitle><jtitle>The journal of physical chemistry. A</jtitle><addtitle>J. Phys. Chem. A</addtitle><date>2013-08-29</date><risdate>2013</risdate><volume>117</volume><issue>34</issue><spage>8126</spage><epage>8131</epage><pages>8126-8131</pages><issn>1089-5639</issn><eissn>1520-5215</eissn><abstract>We report high-resolution anion photoelectron spectra of thiozonide (S3 –) acquired by slow electron velocity-map imaging (SEVI). The ions were cryogenically cooled within an ion trap before photodetachment. We measure an electron affinity of 2.3630(9) eV, resolving discrepancies in previously reported photoelectron spectra that resulted from the presence of vibrational hot bands. The SEVI spectrum shows well-resolved, extended vibrational progressions in the symmetric stretch and bending modes of S3, yielding accurate frequencies for both.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>23461601</pmid><doi>10.1021/jp401083u</doi><tpages>6</tpages></addata></record> |
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| subjects | Atomic and molecular physics Calculations and mathematical techniques in atomic and molecular physics (excluding electron correlation calculations) Coupled cluster theory Electronic structure of atoms, molecules and their ions: theory Exact sciences and technology Ionization potentials, electron affinities, molecular core binding energy Molecular properties and interactions with photons Photoelectron spectra Physics Properties of molecules and molecular ions |
| title | Slow Photoelectron Velocity-Map Imaging Spectroscopy of Cold Thiozonide (S3 –) |
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