Iron-Catalyzed Ring-Closing Depolymerization of Poly(tetrahydrofuran)
Closed encounter: Inexpensive and abundant FeCl3 is demonstrated as an effective pre‐catalyst for the ring‐closing depolymerization of polytetrahydrofuran (polyTHF) to produce tetrahydrofuran (THF) in high purity and good yields. The protocol is of interest for efficient waste management of end‐life...
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Veröffentlicht in: | ChemSusChem 2013-08, Vol.6 (8), p.1334-1336 |
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description | Closed encounter: Inexpensive and abundant FeCl3 is demonstrated as an effective pre‐catalyst for the ring‐closing depolymerization of polytetrahydrofuran (polyTHF) to produce tetrahydrofuran (THF) in high purity and good yields. The protocol is of interest for efficient waste management of end‐life polyTHF, and the produced THF is a suitable starting material for new polymeric materials, allowing for an overall efficient recycling process |
doi_str_mv | 10.1002/cssc.201300380 |
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The protocol is of interest for efficient waste management of end‐life polyTHF, and the produced THF is a suitable starting material for new polymeric materials, allowing for an overall efficient recycling process</description><subject>Butylene Glycols - chemistry</subject><subject>Catalysis</subject><subject>Chlorides - chemistry</subject><subject>depolymerization</subject><subject>Ferric Compounds - chemistry</subject><subject>iron</subject><subject>Iron - chemistry</subject><subject>Polymerization</subject><subject>polymers</subject><subject>Polymers - chemistry</subject><subject>ring closing</subject><issn>1864-5631</issn><issn>1864-564X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkM1Lw0AQxRdR_KhePUrBSz2k7s5m83GUqG2hqFhF8bJs0lmNptm6m6DpX29KtYgXT2-Y-b3H8Ag5ZLTPKIXTzLmsD5RxSnlEN8guiwLfE4H_uLmeOdshe869UhrQOAi2yQ7wCJjw2S65GFlTeomqVNEscNq9zctnLymMa7V7jnNTNDO0-UJVuSm7Rndv2k2vwsqql2Zqja6tKk_2yZZWhcODb-2Q-8uLu2Toja8Ho-Rs7GV-GFIPphkIn6eAaawUppFWWoBgoKK4vdEYhFKhDjKhRcow1ByEgBSjUFNAyHiH9Fa5c2vea3SVnOUuw6JQJZraSeaDz8GPImjR4z_oq6lt2X63pCiLuYC4pforKrPGOYtazm0-U7aRjMplwXJZsFwX3BqOvmPrdIbTNf7TaAvEK-AjL7D5J04mk0nyO9xbeXNX4efaq-ybDEIeCvlwNZB3gXi6HPJEDvgX2PWWTA</recordid><startdate>201308</startdate><enddate>201308</enddate><creator>Enthaler, Stephan</creator><creator>Trautner, Alexandra</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope></search><sort><creationdate>201308</creationdate><title>Iron-Catalyzed Ring-Closing Depolymerization of Poly(tetrahydrofuran)</title><author>Enthaler, Stephan ; Trautner, Alexandra</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4770-2dc2543b2eb9aaeb8faf52512a892dc0925aa7f6c5f5b1e7f32552be87f02e2c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Butylene Glycols - chemistry</topic><topic>Catalysis</topic><topic>Chlorides - chemistry</topic><topic>depolymerization</topic><topic>Ferric Compounds - chemistry</topic><topic>iron</topic><topic>Iron - chemistry</topic><topic>Polymerization</topic><topic>polymers</topic><topic>Polymers - chemistry</topic><topic>ring closing</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Enthaler, Stephan</creatorcontrib><creatorcontrib>Trautner, Alexandra</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>ChemSusChem</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Enthaler, Stephan</au><au>Trautner, Alexandra</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Iron-Catalyzed Ring-Closing Depolymerization of Poly(tetrahydrofuran)</atitle><jtitle>ChemSusChem</jtitle><addtitle>ChemSusChem</addtitle><date>2013-08</date><risdate>2013</risdate><volume>6</volume><issue>8</issue><spage>1334</spage><epage>1336</epage><pages>1334-1336</pages><issn>1864-5631</issn><eissn>1864-564X</eissn><abstract>Closed encounter: Inexpensive and abundant FeCl3 is demonstrated as an effective pre‐catalyst for the ring‐closing depolymerization of polytetrahydrofuran (polyTHF) to produce tetrahydrofuran (THF) in high purity and good yields. The protocol is of interest for efficient waste management of end‐life polyTHF, and the produced THF is a suitable starting material for new polymeric materials, allowing for an overall efficient recycling process</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>23821541</pmid><doi>10.1002/cssc.201300380</doi><tpages>3</tpages></addata></record> |
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subjects | Butylene Glycols - chemistry Catalysis Chlorides - chemistry depolymerization Ferric Compounds - chemistry iron Iron - chemistry Polymerization polymers Polymers - chemistry ring closing |
title | Iron-Catalyzed Ring-Closing Depolymerization of Poly(tetrahydrofuran) |
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