Iron-Catalyzed Ring-Closing Depolymerization of Poly(tetrahydrofuran)

Closed encounter: Inexpensive and abundant FeCl3 is demonstrated as an effective pre‐catalyst for the ring‐closing depolymerization of polytetrahydrofuran (polyTHF) to produce tetrahydrofuran (THF) in high purity and good yields. The protocol is of interest for efficient waste management of end‐life...

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Veröffentlicht in:ChemSusChem 2013-08, Vol.6 (8), p.1334-1336
Hauptverfasser: Enthaler, Stephan, Trautner, Alexandra
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description Closed encounter: Inexpensive and abundant FeCl3 is demonstrated as an effective pre‐catalyst for the ring‐closing depolymerization of polytetrahydrofuran (polyTHF) to produce tetrahydrofuran (THF) in high purity and good yields. The protocol is of interest for efficient waste management of end‐life polyTHF, and the produced THF is a suitable starting material for new polymeric materials, allowing for an overall efficient recycling process
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source MEDLINE; Wiley Online Library Journals Frontfile Complete
subjects Butylene Glycols - chemistry
Catalysis
Chlorides - chemistry
depolymerization
Ferric Compounds - chemistry
iron
Iron - chemistry
Polymerization
polymers
Polymers - chemistry
ring closing
title Iron-Catalyzed Ring-Closing Depolymerization of Poly(tetrahydrofuran)
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