Structural Modification on Copper(I)-pyridylpyrimidine Complexes for Modulation of Rotational Dynamics, Redox Properties, and Phototriggered Isomerization

The redox properties of copper pyridylpyrimidine complexes, which undergo linkage isomerism based on pyrimidine ring rotation, were compared under different coordination environments. A newly synthesized compound, [Cu(Mepypm)(LMes)]BF4 (1·BF4, Mepypm = 4-methyl-2-(2′-pyridyl)pyrimidine, LMes = 2,9-d...

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Veröffentlicht in:	Inorganic chemistry 2013-08, Vol.52 (15), p.8962-8970
Hauptverfasser:	Nishikawa, Michihiro, Takara, Yusuke, Hattori, Yohei, Nomoto, Kuniharu, Kusamoto, Tetsuro, Kume, Shoko, Nishihara, Hiroshi
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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