Dramatic effect of redox pre-treatments on the CO oxidation activity of Au/Ce sub(0.50)Tb sub(0.12)Zr sub(0.38)O sub(2-x) catalysts prepared by deposition-precipitation with urea: a nano-analytical and nano-structural study

Nano-structural and nano-analytical studies show that the dramatic difference in CO oxidation activity observed between two Au/Ce sub(0.50)Tb sub(0.12)Zr sub(0.38)O sub(2-x) samples prepared by deposition-precipitation with urea and further activated under oxidising or reducing conditions is due to...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-07, Vol.49 (60), p.6722-6724
Hauptverfasser: del Rio, Eloy, Lopez-Haro, Miguel, Cies, Jose M, Delgado, Juan J, Calvino, Jose J, Trasobares, Susana, Blanco, Ginesa, Cauqui, Miguel A, Bernal, Serafin
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container_issue 60
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container_title Chemical communications (Cambridge, England)
container_volume 49
creator del Rio, Eloy
Lopez-Haro, Miguel
Cies, Jose M
Delgado, Juan J
Calvino, Jose J
Trasobares, Susana
Blanco, Ginesa
Cauqui, Miguel A
Bernal, Serafin
description Nano-structural and nano-analytical studies show that the dramatic difference in CO oxidation activity observed between two Au/Ce sub(0.50)Tb sub(0.12)Zr sub(0.38)O sub(2-x) samples prepared by deposition-precipitation with urea and further activated under oxidising or reducing conditions is due to the poisoning effect of a very thin layer of carbon grown on the pre-reduced catalyst.
doi_str_mv 10.1039/c3cc42051e
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Carbon monoxide
Catalysis
Deposition
Gold
Nanocomposites
Nanomaterials
Nanostructure
Ureas
title Dramatic effect of redox pre-treatments on the CO oxidation activity of Au/Ce sub(0.50)Tb sub(0.12)Zr sub(0.38)O sub(2-x) catalysts prepared by deposition-precipitation with urea: a nano-analytical and nano-structural study
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