Lanthanide-polyphosphonate coordination polymers combining catalytic and photoluminescence properties
A rapid, mild and high-yield microwave synthesis of 1D isotypical [Ln(H4bmt)(H5bmt)(H2O)2]·3H2O coordination polymers is presented. The La(3+)-based material is highly active as a heterogeneous catalyst in the methanolysis of styrene oxide at nearly room temperature. Eu(3+)- and Tb(3+)-doped materia...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (57), p.6400-6402 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Vilela, Sérgio M F Firmino, Ana D G Mendes, Ricardo F Fernandes, José A Ananias, Duarte Valente, Anabela A Ott, Holger Carlos, Luís D Rocha, João Tomé, João P C Paz, Filipe A Almeida |
| description | A rapid, mild and high-yield microwave synthesis of 1D isotypical [Ln(H4bmt)(H5bmt)(H2O)2]·3H2O coordination polymers is presented. The La(3+)-based material is highly active as a heterogeneous catalyst in the methanolysis of styrene oxide at nearly room temperature. Eu(3+)- and Tb(3+)-doped materials are very effective UV-to-visible light converters. |
| doi_str_mv | 10.1039/c3cc42632g |
| format | Article |
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| ispartof | Chemical communications (Cambridge, England), 2013-01, Vol.49 (57), p.6400-6402 |
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| language | eng |
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| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Catalysis Catalysts Coordination Complexes - chemistry Coordination polymers Lanthanoid Series Elements - chemistry Luminescence Microwaves Organophosphorus Compounds - chemistry Oxides Photoluminescence Styrenes Synthesis |
| title | Lanthanide-polyphosphonate coordination polymers combining catalytic and photoluminescence properties |
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