Digital compressive chemical quantitation and hyperspectral imaging

Digital compressive detection, implemented using optimized binary (OB) filters, is shown to greatly increase the speed at which Raman spectroscopy can be used to quantify the composition of liquid mixtures and to chemically image mixed solid powders. We further demonstrate that OB filters can be pro...

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Veröffentlicht in:Analyst (London) 2013-09, Vol.138 (17), p.4982-499
Hauptverfasser: Wilcox, David S, Buzzard, Gregery T, Lucier, Bradley J, Rehrauer, Owen G, Wang, Ping, Ben-Amotz, Dor
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container_issue 17
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container_title Analyst (London)
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creator Wilcox, David S
Buzzard, Gregery T
Lucier, Bradley J
Rehrauer, Owen G
Wang, Ping
Ben-Amotz, Dor
description Digital compressive detection, implemented using optimized binary (OB) filters, is shown to greatly increase the speed at which Raman spectroscopy can be used to quantify the composition of liquid mixtures and to chemically image mixed solid powders. We further demonstrate that OB filters can be produced using multivariate curve resolution (MCR) to pre-process mixture training spectra, thus facilitating the quantitation of mixtures even when no pure chemical component samples are available for training. Optimal binary compressive detection is used to rapidly quantify the composition of liquid mixtures and to chemically image mixed solid powders.
doi_str_mv 10.1039/c3an00309d
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source Royal Society of Chemistry Journals Archive (1841-2007); Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Digital
Hyperspectral imaging
Image detection
Liquids
Raman spectroscopy
Spectra
Training
title Digital compressive chemical quantitation and hyperspectral imaging
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