Tandem Ring-Opening/Ring-Closing Metathesis Polymerization: Relationship between Monomer Structure and Reactivity

Monomers containing either cycloalkenes with low ring strain or 1-alkynes are poor monomers for olefin metathesis polymerization. Ironically, keeping two inactive functional groups in proximity within one molecule can make it an excellent monomer for metathesis polymerization. Recently, we demonstra...

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Veröffentlicht in:Journal of the American Chemical Society 2013-07, Vol.135 (29), p.10769-10775
Hauptverfasser: Park, Hyeon, Lee, Ho-Keun, Choi, Tae-Lim
Format: Artikel
Sprache:eng
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