Metal-Free HB(C6F5)2-Catalyzed Hydrogenation of Unfunctionalized Olefins and Mechanism Study of Borane-Mediated σ-Bond Metathesis

Metal-Free HB(C6F5)2-Catalyzed Hydrogenation of Unfunctionalized Olefins and Mechanism Study of Borane-Mediated σ-Bond Metathesis

Out with the metal: Metal‐free hydrogenation of unfunctionalized olefins can be achieved by employing HB(C6F5)2 as the catalyst. The key step in the catalytic reaction is believed to involve a novel borane‐mediated σ‐bond metathesis, which has been investigated both experimentally and theoretically....

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Veröffentlicht in:Angewandte Chemie International Edition 2013-07, Vol.52 (29), p.7496-7499
Hauptverfasser: Wang, Yuwen, Chen, Weiqiang, Lu, Zhenpin, Li, Zhen Hua, Wang, Huadong
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Sprache:eng
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alkenes
boron
hydrogenation
metathesis
synthetic methods
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container_issue 29
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container_title Angewandte Chemie International Edition
container_volume 52
creator Wang, Yuwen
Chen, Weiqiang
Lu, Zhenpin
Li, Zhen Hua
Wang, Huadong
description Out with the metal: Metal‐free hydrogenation of unfunctionalized olefins can be achieved by employing HB(C6F5)2 as the catalyst. The key step in the catalytic reaction is believed to involve a novel borane‐mediated σ‐bond metathesis, which has been investigated both experimentally and theoretically.
doi_str_mv 10.1002/anie.201303500
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subjects alkenes
boron
hydrogenation
metathesis
synthetic methods
title Metal-Free HB(C6F5)2-Catalyzed Hydrogenation of Unfunctionalized Olefins and Mechanism Study of Borane-Mediated σ-Bond Metathesis
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