Polyurethanes from Isosorbide-Based Diisocyanates

Polyurethanes from Isosorbide-Based Diisocyanates

Benign building blocks: Stereochemically pure diisocyanates were prepared on a multigram scale from succinic anhydride and isosorbide or isomannide. Characterization of polyurethanes that were produced from these diisocyanates revealed low polydispersity, high thermal stability, and stereochemistry‐...

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Veröffentlicht in:ChemSusChem 2013-07, Vol.6 (7), p.1182-1185
Hauptverfasser: Zenner, Michael D., Xia, Ying, Chen, Jason S., Kessler, Michael R.
Format: Artikel
Sprache:eng
Schlagworte:
green chemistry
isocyanates
Isosorbide - chemistry
Nitriles - chemistry
polymers
Polyurethanes - chemical synthesis
Polyurethanes - chemistry
rearrangement
renewable resources
Temperature
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container_issue 7
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container_title ChemSusChem
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creator Zenner, Michael D.
Xia, Ying
Chen, Jason S.
Kessler, Michael R.
description Benign building blocks: Stereochemically pure diisocyanates were prepared on a multigram scale from succinic anhydride and isosorbide or isomannide. Characterization of polyurethanes that were produced from these diisocyanates revealed low polydispersity, high thermal stability, and stereochemistry‐dependent morphology. If biobased succinic anhydride is used, then no stoichiometric petroleum‐derived reagents are required in the synthesis of these materials.
doi_str_mv 10.1002/cssc.201300126
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source MEDLINE; Wiley Online Library All Journals
subjects green chemistry
isocyanates
Isosorbide - chemistry
Nitriles - chemistry
polymers
Polyurethanes - chemical synthesis
Polyurethanes - chemistry
rearrangement
renewable resources
Temperature
title Polyurethanes from Isosorbide-Based Diisocyanates
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