Superhydrophobic perfluorinated metal-organic frameworks

Three perfluorinated Cu-based metal-organic frameworks (MOFs) were prepared starting from extensively fluorinated biphenyl-based ligands accessed via C-H functionalization. These new materials are highly hydrophobic: with water contact angles of up to 151 ± 1°, they are among the most water-repellen...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-08, Vol.49 (61), p.6846-6848
Hauptverfasser: Chen, Teng-Hao, Popov, Ilya, Zenasni, Oussama, Daugulis, Olafs, Miljanić, Ognjen Š
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container_issue 61
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container_title Chemical communications (Cambridge, England)
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creator Chen, Teng-Hao
Popov, Ilya
Zenasni, Oussama
Daugulis, Olafs
Miljanić, Ognjen Š
description Three perfluorinated Cu-based metal-organic frameworks (MOFs) were prepared starting from extensively fluorinated biphenyl-based ligands accessed via C-H functionalization. These new materials are highly hydrophobic: with water contact angles of up to 151 ± 1°, they are among the most water-repellent MOFs ever reported.
doi_str_mv 10.1039/c3cc41564c
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source MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Copper - chemistry
Hydrophobic and Hydrophilic Interactions
Models, Molecular
Molecular Structure
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
title Superhydrophobic perfluorinated metal-organic frameworks
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