Persistence and fate of methyl parathion in sea water
Experiments are described to assess the effect of salt content, settled sewage, and pH on the stability and fate of the pesticide methyl parathion. Whilst it was relatively stable under acidic conditions, increased hydrolysis occurred under neutral conditions at pH8.5. Rates of hydrolysis decreased...
Gespeichert in:
Veröffentlicht in: | Bulletin of environmental contamination and toxicology 1984-07, Vol.33 (1), p.40-49 |
---|---|
Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 49 |
---|---|
container_issue | 1 |
container_start_page | 40 |
container_title | Bulletin of environmental contamination and toxicology |
container_volume | 33 |
creator | Badawy, M.I El-Dib, M.A |
description | Experiments are described to assess the effect of salt content, settled sewage, and pH on the stability and fate of the pesticide methyl parathion. Whilst it was relatively stable under acidic conditions, increased hydrolysis occurred under neutral conditions at pH8.5. Rates of hydrolysis decreased with increased salt content although sodium chloride did not seem to be involved. In samples containing settled sewage rates of biodegradation were initially slow, however as the bacterial population adapted to the insecticide, degradation was achieved in relatively short periods. The degradation pathways included the reduction of the nitro group, dealkylation and hydrolysis of the ester linkage. |
doi_str_mv | 10.1007/BF01625509 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_13836039</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>13836039</sourcerecordid><originalsourceid>FETCH-LOGICAL-c361t-1ca0c7bbfaf0f6b3d1af52cc76502f8999d6400bff749e6165bb9afa3170abd23</originalsourceid><addsrcrecordid>eNpF0MFLwzAUx_EgypzTi0dByEE8CNWXpEmbow6nwkBBdy4vaeIqXTuTDtl_b2Vlnt7h--EdfoScM7hlANndwwyY4lKCPiBjlgqeQA5wSMbQ1yTNFTsmJzF-ATCZcz4iI9UjyLIxkW8uxCp2rrGOYlNSj52jracr1y23NV1jwG5ZtQ2tGhod0p--h1Ny5LGO7my4E7KYPX5Mn5P569PL9H6eWKFYlzCLYDNjPHrwyoiSoZfc2kxJ4D7XWpcqBTDeZ6l2iilpjEaPgmWApuRiQq53f9eh_d642BWrKlpX19i4dhMLJnKhQOge3uygDW2MwfliHaoVhm3BoPjbqPjfqMeXw9eNWblyT4dR-n41dIwWax-wsVXcs1yDBiV7drFjHtsCP0NPFu-5FDznWvwCeOh04w</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>13836039</pqid></control><display><type>article</type><title>Persistence and fate of methyl parathion in sea water</title><source>MEDLINE</source><source>Springer Online Journals Complete</source><creator>Badawy, M.I ; El-Dib, M.A</creator><creatorcontrib>Badawy, M.I ; El-Dib, M.A</creatorcontrib><description>Experiments are described to assess the effect of salt content, settled sewage, and pH on the stability and fate of the pesticide methyl parathion. Whilst it was relatively stable under acidic conditions, increased hydrolysis occurred under neutral conditions at pH8.5. Rates of hydrolysis decreased with increased salt content although sodium chloride did not seem to be involved. In samples containing settled sewage rates of biodegradation were initially slow, however as the bacterial population adapted to the insecticide, degradation was achieved in relatively short periods. The degradation pathways included the reduction of the nitro group, dealkylation and hydrolysis of the ester linkage.</description><identifier>ISSN: 0007-4861</identifier><identifier>EISSN: 1432-0800</identifier><identifier>DOI: 10.1007/BF01625509</identifier><identifier>PMID: 6432077</identifier><identifier>CODEN: BECTA6</identifier><language>eng</language><publisher>New York, NY: Springer-Verlag</publisher><subject>Applied sciences ; Biodegradation, Environmental ; Carbon Dioxide - analysis ; Drug Stability ; Exact sciences and technology ; Fresh Water - analysis ; Hydrogen-Ion Concentration ; Hydrolysis ; Kinetics ; Methyl Parathion - analysis ; Natural water pollution ; Parathion - analogs & derivatives ; Pollution ; Seawater - analysis ; Seawaters, estuaries ; Sodium Chloride - analysis ; Temperature ; Water Pollutants - analysis ; Water Pollutants, Chemical - analysis ; Water treatment and pollution</subject><ispartof>Bulletin of environmental contamination and toxicology, 1984-07, Vol.33 (1), p.40-49</ispartof><rights>1985 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c361t-1ca0c7bbfaf0f6b3d1af52cc76502f8999d6400bff749e6165bb9afa3170abd23</citedby><cites>FETCH-LOGICAL-c361t-1ca0c7bbfaf0f6b3d1af52cc76502f8999d6400bff749e6165bb9afa3170abd23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,27929,27930</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=8909065$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/6432077$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Badawy, M.I</creatorcontrib><creatorcontrib>El-Dib, M.A</creatorcontrib><title>Persistence and fate of methyl parathion in sea water</title><title>Bulletin of environmental contamination and toxicology</title><addtitle>Bull Environ Contam Toxicol</addtitle><description>Experiments are described to assess the effect of salt content, settled sewage, and pH on the stability and fate of the pesticide methyl parathion. Whilst it was relatively stable under acidic conditions, increased hydrolysis occurred under neutral conditions at pH8.5. Rates of hydrolysis decreased with increased salt content although sodium chloride did not seem to be involved. In samples containing settled sewage rates of biodegradation were initially slow, however as the bacterial population adapted to the insecticide, degradation was achieved in relatively short periods. The degradation pathways included the reduction of the nitro group, dealkylation and hydrolysis of the ester linkage.</description><subject>Applied sciences</subject><subject>Biodegradation, Environmental</subject><subject>Carbon Dioxide - analysis</subject><subject>Drug Stability</subject><subject>Exact sciences and technology</subject><subject>Fresh Water - analysis</subject><subject>Hydrogen-Ion Concentration</subject><subject>Hydrolysis</subject><subject>Kinetics</subject><subject>Methyl Parathion - analysis</subject><subject>Natural water pollution</subject><subject>Parathion - analogs & derivatives</subject><subject>Pollution</subject><subject>Seawater - analysis</subject><subject>Seawaters, estuaries</subject><subject>Sodium Chloride - analysis</subject><subject>Temperature</subject><subject>Water Pollutants - analysis</subject><subject>Water Pollutants, Chemical - analysis</subject><subject>Water treatment and pollution</subject><issn>0007-4861</issn><issn>1432-0800</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1984</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpF0MFLwzAUx_EgypzTi0dByEE8CNWXpEmbow6nwkBBdy4vaeIqXTuTDtl_b2Vlnt7h--EdfoScM7hlANndwwyY4lKCPiBjlgqeQA5wSMbQ1yTNFTsmJzF-ATCZcz4iI9UjyLIxkW8uxCp2rrGOYlNSj52jracr1y23NV1jwG5ZtQ2tGhod0p--h1Ny5LGO7my4E7KYPX5Mn5P569PL9H6eWKFYlzCLYDNjPHrwyoiSoZfc2kxJ4D7XWpcqBTDeZ6l2iilpjEaPgmWApuRiQq53f9eh_d642BWrKlpX19i4dhMLJnKhQOge3uygDW2MwfliHaoVhm3BoPjbqPjfqMeXw9eNWblyT4dR-n41dIwWax-wsVXcs1yDBiV7drFjHtsCP0NPFu-5FDznWvwCeOh04w</recordid><startdate>198407</startdate><enddate>198407</enddate><creator>Badawy, M.I</creator><creator>El-Dib, M.A</creator><general>Springer-Verlag</general><scope>FBQ</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope></search><sort><creationdate>198407</creationdate><title>Persistence and fate of methyl parathion in sea water</title><author>Badawy, M.I ; El-Dib, M.A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c361t-1ca0c7bbfaf0f6b3d1af52cc76502f8999d6400bff749e6165bb9afa3170abd23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1984</creationdate><topic>Applied sciences</topic><topic>Biodegradation, Environmental</topic><topic>Carbon Dioxide - analysis</topic><topic>Drug Stability</topic><topic>Exact sciences and technology</topic><topic>Fresh Water - analysis</topic><topic>Hydrogen-Ion Concentration</topic><topic>Hydrolysis</topic><topic>Kinetics</topic><topic>Methyl Parathion - analysis</topic><topic>Natural water pollution</topic><topic>Parathion - analogs & derivatives</topic><topic>Pollution</topic><topic>Seawater - analysis</topic><topic>Seawaters, estuaries</topic><topic>Sodium Chloride - analysis</topic><topic>Temperature</topic><topic>Water Pollutants - analysis</topic><topic>Water Pollutants, Chemical - analysis</topic><topic>Water treatment and pollution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Badawy, M.I</creatorcontrib><creatorcontrib>El-Dib, M.A</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aqualine</collection><jtitle>Bulletin of environmental contamination and toxicology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Badawy, M.I</au><au>El-Dib, M.A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Persistence and fate of methyl parathion in sea water</atitle><jtitle>Bulletin of environmental contamination and toxicology</jtitle><addtitle>Bull Environ Contam Toxicol</addtitle><date>1984-07</date><risdate>1984</risdate><volume>33</volume><issue>1</issue><spage>40</spage><epage>49</epage><pages>40-49</pages><issn>0007-4861</issn><eissn>1432-0800</eissn><coden>BECTA6</coden><abstract>Experiments are described to assess the effect of salt content, settled sewage, and pH on the stability and fate of the pesticide methyl parathion. Whilst it was relatively stable under acidic conditions, increased hydrolysis occurred under neutral conditions at pH8.5. Rates of hydrolysis decreased with increased salt content although sodium chloride did not seem to be involved. In samples containing settled sewage rates of biodegradation were initially slow, however as the bacterial population adapted to the insecticide, degradation was achieved in relatively short periods. The degradation pathways included the reduction of the nitro group, dealkylation and hydrolysis of the ester linkage.</abstract><cop>New York, NY</cop><pub>Springer-Verlag</pub><pmid>6432077</pmid><doi>10.1007/BF01625509</doi><tpages>10</tpages></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0007-4861 |
ispartof | Bulletin of environmental contamination and toxicology, 1984-07, Vol.33 (1), p.40-49 |
issn | 0007-4861 1432-0800 |
language | eng |
recordid | cdi_proquest_miscellaneous_13836039 |
source | MEDLINE; Springer Online Journals Complete |
subjects | Applied sciences Biodegradation, Environmental Carbon Dioxide - analysis Drug Stability Exact sciences and technology Fresh Water - analysis Hydrogen-Ion Concentration Hydrolysis Kinetics Methyl Parathion - analysis Natural water pollution Parathion - analogs & derivatives Pollution Seawater - analysis Seawaters, estuaries Sodium Chloride - analysis Temperature Water Pollutants - analysis Water Pollutants, Chemical - analysis Water treatment and pollution |
title | Persistence and fate of methyl parathion in sea water |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-15T07%3A10%3A08IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Persistence%20and%20fate%20of%20methyl%20parathion%20in%20sea%20water&rft.jtitle=Bulletin%20of%20environmental%20contamination%20and%20toxicology&rft.au=Badawy,%20M.I&rft.date=1984-07&rft.volume=33&rft.issue=1&rft.spage=40&rft.epage=49&rft.pages=40-49&rft.issn=0007-4861&rft.eissn=1432-0800&rft.coden=BECTA6&rft_id=info:doi/10.1007/BF01625509&rft_dat=%3Cproquest_cross%3E13836039%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=13836039&rft_id=info:pmid/6432077&rfr_iscdi=true |