Room-temperature proton transport and its effect on thermopower in a solid ionic semiconductor, TTFCOONH sub(4)

Ammonium proton in a solid ionic semiconductor, TTFCOONH sub(4), is shown to be mobile under anhydrous conditions at room temperature by the hydrogen concentration cell method. Isotope substituted TTFCOOND sub(4) exhibits a 2.2 H/D isotope effect in ion carrier mobility with TTFCOONH sub(4). First-p...

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Veröffentlicht in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2013-03, Vol.1 (16), p.5089-5096
Hauptverfasser: Kobayashi, Yuka, Fujii, Takenori, Terasaki, Ichiro, Kino, Hiori, Jin, Yongcheng, Hibino, Takashi, Kobayashi, Tetsuya, Nishibori, Eiji, Sawa, Hiroshi, Yoshikawa, Hideki, Terauchi, Takeshi, Sumi, Satoshi
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Sprache:eng
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