Physicochemical and ecotoxicological based assessment of bottom sediments from the Luján River basin, Buenos Aires, Argentina

The physicochemical analysis of bottom sediments of the Lujan River was done on samples from 14 sites situated along its course and covered grain size and organic matter, total N and P, sulfides, heavy metals, organochlorine, and pyrethroid pesticides. In addition, acute 10-day whole-sediment labora...

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Veröffentlicht in:Environmental monitoring and assessment 2013-07, Vol.185 (7), p.5993-6002
Hauptverfasser: Peluso, Leticia, Bulus Rossini, Gustavo, Salibián, Alfredo, Ronco, Alicia
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Bulus Rossini, Gustavo
Salibián, Alfredo
Ronco, Alicia
description The physicochemical analysis of bottom sediments of the Lujan River was done on samples from 14 sites situated along its course and covered grain size and organic matter, total N and P, sulfides, heavy metals, organochlorine, and pyrethroid pesticides. In addition, acute 10-day whole-sediment laboratory toxicity tests were carried with each sample, using the native amphipod Hyalella curvispina as test organism. In order to correlate both types of results, data were assessed by multivariate analysis, including principal component analysis (PCA). The physicochemical profile of samples resulted similar along the river course, though several anomalous data were registered in the middle course of the river, mainly in samples taken downstream a large industrial complex; with a few exceptions in upper basin sites characterized by the dominance of agricultural activities, the pesticides concentration were consistently below the analytical detection limits. Almost 50 % of the samples induced adverse effects on the amphipod when testing sublethal and lethal end points. The toxicity of the samples in terms of survival rate was extremely high in two sites, in particular in samples taken downstream the Pilar industrial complex. The integration of a selection of physicochemical and toxicological parameters of the sediments by PCA allowed discriminating areas of the river basin according the type and intensity of their particular pollution condition.
doi_str_mv 10.1007/s10661-012-3000-7
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subjects Agrochemicals
Analysis
Animal, plant and microbial ecology
Applied ecology
Argentina
Atmospheric Protection/Air Quality Control/Air Pollution
Biological and medical sciences
Bottom sediments
Conservation, protection and management of environment and wildlife
Contaminated sediments
Detection limits
Earth and Environmental Science
Ecology
Ecotoxicology
Ecotoxicology, biological effects of pollution
Environment
Environmental Management
Environmental Monitoring
Freshwater
Fundamental and applied biological sciences. Psychology
Geologic Sediments - chemistry
Grain size
Heavy metals
Hyalella curvispina
Laboratories
Metals, Heavy - analysis
Metals, Heavy - toxicity
Monitoring/Environmental Analysis
Multivariate analysis
Organic compounds
Organic matter
Pesticides
Pesticides - analysis
Pesticides - toxicity
Physicochemical analysis
Pollutants
Principal components analysis
Pyrethroids
River basins
Rivers
Rivers - chemistry
Sediments
Studies
Survival
Toxicity
Water Pollutants, Chemical - analysis
Water Pollutants, Chemical - toxicity
title Physicochemical and ecotoxicological based assessment of bottom sediments from the Luján River basin, Buenos Aires, Argentina
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