A Ru−η6‑Arene Complex as a C‑Based Lewis Acid in the Activation of Hydrogen and Hydrogenation Catalysis

The PBP ligand (Ph2PC6H4)2BPh was used to prepare ((Ph2PC6H4)2B(Cl)(η6-Ph)RuCl (1) and subsequently [((Ph2PC6H4)2B(η6-Ph))RuCl]­[B(C6F5)4] (2). The latter species exhibited Lewis acidity on the η6-Ph ring, as reaction with Cy3P gave the donor–acceptor adduct [(Ph2PC6H4)2B(η5-C6H5-o-PCy3)RuCl]­[B(C6F...

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Veröffentlicht in:	Journal of the American Chemical Society 2013-06, Vol.135 (23), p.8508-8511
Hauptverfasser:	Boone, Michael P, Stephan, Douglas W
Format:	Artikel
Sprache:	eng
Schlagworte:	Boranes - chemistry Catalysis Crystallography, X-Ray Hydrogen - chemistry Hydrogenation Lewis Acids - chemistry Models, Molecular Molecular Conformation Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Quantum Theory Ruthenium - chemistry
Online-Zugang:	Volltext
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