Controlling porous properties of polymer monoliths synthesized by photoinitiated polymerization

Porous monoliths have been successfully prepared by photoinitiated polymerization of hydroxyethyl methacrylate and ethylene glycol dimethacrylate monomers in a porogenic solvent. By varying the composition of the starting solutions such as initiator fraction, monomer ratio and pore generator (poroge...

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Veröffentlicht in:Polymer international 2013-03, Vol.62 (3), p.406-410
Hauptverfasser: Yu, Suzhu, Ma, Khin Cho Cho, Mon, Aye Aye, Ng, Fern Lan, Ng, Yen Yong
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container_end_page 410
container_issue 3
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container_title Polymer international
container_volume 62
creator Yu, Suzhu
Ma, Khin Cho Cho
Mon, Aye Aye
Ng, Fern Lan
Ng, Yen Yong
description Porous monoliths have been successfully prepared by photoinitiated polymerization of hydroxyethyl methacrylate and ethylene glycol dimethacrylate monomers in a porogenic solvent. By varying the composition of the starting solutions such as initiator fraction, monomer ratio and pore generator (porogen) fraction and type, as well as UV intensity, monoliths have been obtained with narrow pore size distribution and median pore size from about a few nanometres to a few micrometres. © 2012 Society of Chemical Industry Porous monoliths, prepared by photoinitiated polymerization, have a narrow pore size distribution and median pore size from a few nanometres to a few micrometres depending on the composition of the starting solution.
doi_str_mv 10.1002/pi.4322
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subjects Applied sciences
Ethylene glycol
Exact sciences and technology
filtration
Initiators
microfluidics
Monomers
Organic polymers
photoinitiated polymerization
Physicochemistry of polymers
Polyhydroxyethyl methacrylate
Polymerization
Polymers with particular structures
Pore size
Porosity
porous polymers
porous properties
Preparation, kinetics, thermodynamics, mechanism and catalysts
Solvents
title Controlling porous properties of polymer monoliths synthesized by photoinitiated polymerization
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