Highly ordered, ultra long nanofibrils viathe hierarchical self-assembly of ionic aromatic oligoamides
Highly ordered templates are of great importance in fabricating well-arranged nanomaterials. Inspired by the hierarchical assembly of bio-macromolecules, we designed a water soluble three-arm ionic aromatic oligoamide which can spontaneously self-assemble into bundles of nanofibrils. Unlike conventi...
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| Veröffentlicht in: | Soft matter 2013-04, Vol.9 (18), p.4642-4647 |
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| container_issue | 18 |
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| container_title | Soft matter |
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| creator | Li, Junjun Huang, Ningdong Wang, Daoliang Xu, Lu Huang, Youju Chen, Mingming Tao, Jiaojiao Pan, Guoqiang Wu, Ziyu Li, Liangbin |
| description | Highly ordered templates are of great importance in fabricating well-arranged nanomaterials. Inspired by the hierarchical assembly of bio-macromolecules, we designed a water soluble three-arm ionic aromatic oligoamide which can spontaneously self-assemble into bundles of nanofibrils. Unlike conventional assemblies formed by synthetic oligoamides individually dispersed in solution, the nanofibrils in our present study tend to further arrange into orthorhombic arrays and form microfibers that can be up to millimeters in length. The surrounding ions play a key role in assembly behavior and possess a high metal-ion binding capacity, which provides a strategy for tuning ordered structures of functional materials and possibilities for understanding the assembly mechanism of biological counterparts. |
| doi_str_mv | 10.1039/c3sm50390a |
| format | Article |
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| fulltext | fulltext |
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| ispartof | Soft matter, 2013-04, Vol.9 (18), p.4642-4647 |
| issn | 1744-683X 1744-6848 |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Arrays Assembly Nanocomposites Nanomaterials Nanostructure Self assembly Strategy Tuning |
| title | Highly ordered, ultra long nanofibrils viathe hierarchical self-assembly of ionic aromatic oligoamides |
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