Enhanced ferroelectric and dielectric properties in (La0.7Ca0.3)MnO3-buffered (Bi0.5Na0.5)TiO3-based lead-free thin film by pulsed laser deposition

► LCMO was introduced to promote the crystalline and growth of BNBMT film. ► Large remnant polarization (∼20μC/cm2) comparable to the bulk one was obtained. ► Low dielectric loss was obtained. Mn-doped 0.935(Bi0.5Na0.5)TiO3–0.065BaTiO3 (BNBMT) thin film with a composition near the morphotropic phase...

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Veröffentlicht in:Journal of alloys and compounds 2013-03, Vol.553, p.142-145
Hauptverfasser: Jin, C.C., Wang, F.F., Yao, Q.R., Tang, Y.X., Wang, T., Shi, W.Z.
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container_end_page 145
container_issue
container_start_page 142
container_title Journal of alloys and compounds
container_volume 553
creator Jin, C.C.
Wang, F.F.
Yao, Q.R.
Tang, Y.X.
Wang, T.
Shi, W.Z.
description ► LCMO was introduced to promote the crystalline and growth of BNBMT film. ► Large remnant polarization (∼20μC/cm2) comparable to the bulk one was obtained. ► Low dielectric loss was obtained. Mn-doped 0.935(Bi0.5Na0.5)TiO3–0.065BaTiO3 (BNBMT) thin film with a composition near the morphotropic phase boundary was grown on Pt/Ti/SiO2/Si substrates by using pulsed laser deposition. It was found that the presence of a buffer layer of (La0.7Ca0.3)MnO3 promoted growth of (110)-oriented thin film instead of (100) one. Enhanced ferroelectric properties were obtained for the bilayered film, with remnant polarization Pr of ∼20μC/cm2 and coercive field Ec of ∼10.2kV/mm. Dielectric loss was about 0.10 between 100Hz and 100kHz. The enhanced electrical properties exhibit potential in environmental-friendly ferroelectric devices.
doi_str_mv 10.1016/j.jallcom.2012.11.095
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Mn-doped 0.935(Bi0.5Na0.5)TiO3–0.065BaTiO3 (BNBMT) thin film with a composition near the morphotropic phase boundary was grown on Pt/Ti/SiO2/Si substrates by using pulsed laser deposition. It was found that the presence of a buffer layer of (La0.7Ca0.3)MnO3 promoted growth of (110)-oriented thin film instead of (100) one. Enhanced ferroelectric properties were obtained for the bilayered film, with remnant polarization Pr of ∼20μC/cm2 and coercive field Ec of ∼10.2kV/mm. Dielectric loss was about 0.10 between 100Hz and 100kHz. 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source ScienceDirect Journals (5 years ago - present)
subjects Coercive force
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Devices
Dielectric loss
Dielectric loss and relaxation
Dielectric properties of solids and liquids
Dielectric response
Dielectrics, piezoelectrics, and ferroelectrics and their properties
Exact sciences and technology
Ferroelectric materials
Ferroelectricity
Ferroelectricity and antiferroelectricity
Ferroelectrics
Laser processing
Phase boundaries
Physics
Pulsed laser deposition
Thin film
Thin films
title Enhanced ferroelectric and dielectric properties in (La0.7Ca0.3)MnO3-buffered (Bi0.5Na0.5)TiO3-based lead-free thin film by pulsed laser deposition
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