Synthesis and self-organization of amphiphilic poly(N-vinylpyrrolidone-2,2,3,3-tetrafluoropropyl methacrylate) diblock copolymers in solution and bulk
It is shown that the amphiphilic diblock copolymers poly( N -vinylpyrrolidone-2,2,3,3-tetrafluoropropyl methacrylate) can be prepared through the reaction of chain transfer to bis(pentafluorophenyl)germane during the polymerization of N -vinylpyrrolidone and the subsequent postpolymerization of isol...
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| Veröffentlicht in: | Polymer science. Series A, Chemistry, physics Chemistry, physics, 2011-08, Vol.53 (8), p.691-697 |
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| container_title | Polymer science. Series A, Chemistry, physics |
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| creator | Zamyshlyayeva, O. G. Deniskina, I. V. Filippov, A. P. Semchikov, Yu. D. |
| description | It is shown that the amphiphilic diblock copolymers poly(
N
-vinylpyrrolidone-2,2,3,3-tetrafluoropropyl methacrylate) can be prepared through the reaction of chain transfer to bis(pentafluorophenyl)germane during the polymerization of
N
-vinylpyrrolidone and the subsequent postpolymerization of isolated functional polymers in 2,2,3,3-tetrafluoropropyl methacrylate. The dilute-solution behavior and self-organizing ability of functional polymers based on poly(
N
-vinylpyrrolidone) containing end bis(pentafluorophenyl) groups and of amphiphilic diblock copolymers formed on their basis are studied via the methods of static and dynamic light scattering and viscometry. Surface properties at the interface of the films are estimated through the wetting technique. |
| doi_str_mv | 10.1134/S0965545X11080128 |
| format | Article |
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N
-vinylpyrrolidone-2,2,3,3-tetrafluoropropyl methacrylate) can be prepared through the reaction of chain transfer to bis(pentafluorophenyl)germane during the polymerization of
N
-vinylpyrrolidone and the subsequent postpolymerization of isolated functional polymers in 2,2,3,3-tetrafluoropropyl methacrylate. The dilute-solution behavior and self-organizing ability of functional polymers based on poly(
N
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N
-vinylpyrrolidone-2,2,3,3-tetrafluoropropyl methacrylate) can be prepared through the reaction of chain transfer to bis(pentafluorophenyl)germane during the polymerization of
N
-vinylpyrrolidone and the subsequent postpolymerization of isolated functional polymers in 2,2,3,3-tetrafluoropropyl methacrylate. The dilute-solution behavior and self-organizing ability of functional polymers based on poly(
N
-vinylpyrrolidone) containing end bis(pentafluorophenyl) groups and of amphiphilic diblock copolymers formed on their basis are studied via the methods of static and dynamic light scattering and viscometry. Surface properties at the interface of the films are estimated through the wetting technique.</description><subject>Chain transfer</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Copolymers</subject><subject>Dynamic tests</subject><subject>Dynamics</subject><subject>Polymer Sciences</subject><subject>Polymerization</subject><subject>Structure and Properties</subject><subject>Surface properties</subject><subject>Synthesis</subject><subject>Viscometry</subject><issn>0965-545X</issn><issn>1757-1820</issn><issn>1555-6107</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9kd-K1TAQxosoeFj3AbzLjbDCyZppOm3PpSyuCoterIJ3JU0ne-KmSU3ahfogPq-pZ_FGEAYS-H7zzb-ieAniEkBWb27FoUas8BuAaAWU7ZNiB4jIaxDN02K3yXzTnxfnKdleANQiA9Wu-HW7-vlIySam_MASOcNDvFPe_lSzDZ4Fw9Q4HW0OZzWbglsvPvEH61c3rTEGZ4fgiZf7ci_3ks80R2XcEmKYcqyOjTQflY6rUzO9ZoPtXdD3TIfNaaSYmPUsBbf8qbb10C_u_kXxzCiX6PzxPSu-Xr_7cvWB33x-__Hq7Q3Xsmlnjr2pdF-apkWsiQgUNb3WLeYPoIChFkaSaXtTahqaGlspjSHShwOolgZ5VlycfHOzPxZKczfapMk55SksqQNZI-RtYZ1ROKE6hpQimW6KdlRx7UB02xm6f86Qc1492quklTNReW3T38SyQjwglpkrT1zKkr-j2H0PS_R58v-Y_wbB45uy</recordid><startdate>20110801</startdate><enddate>20110801</enddate><creator>Zamyshlyayeva, O. G.</creator><creator>Deniskina, I. V.</creator><creator>Filippov, A. P.</creator><creator>Semchikov, Yu. D.</creator><general>SP MAIK Nauka/Interperiodica</general><general>Springer</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20110801</creationdate><title>Synthesis and self-organization of amphiphilic poly(N-vinylpyrrolidone-2,2,3,3-tetrafluoropropyl methacrylate) diblock copolymers in solution and bulk</title><author>Zamyshlyayeva, O. G. ; Deniskina, I. V. ; Filippov, A. P. ; Semchikov, Yu. D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c378t-5bf4cb2f78556eee1ae7bcc851ae1501d60f3ef8bf2ced765833ffeec991a8ed3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Chain transfer</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Copolymers</topic><topic>Dynamic tests</topic><topic>Dynamics</topic><topic>Polymer Sciences</topic><topic>Polymerization</topic><topic>Structure and Properties</topic><topic>Surface properties</topic><topic>Synthesis</topic><topic>Viscometry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zamyshlyayeva, O. G.</creatorcontrib><creatorcontrib>Deniskina, I. V.</creatorcontrib><creatorcontrib>Filippov, A. P.</creatorcontrib><creatorcontrib>Semchikov, Yu. D.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer science. Series A, Chemistry, physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zamyshlyayeva, O. G.</au><au>Deniskina, I. V.</au><au>Filippov, A. P.</au><au>Semchikov, Yu. D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and self-organization of amphiphilic poly(N-vinylpyrrolidone-2,2,3,3-tetrafluoropropyl methacrylate) diblock copolymers in solution and bulk</atitle><jtitle>Polymer science. Series A, Chemistry, physics</jtitle><stitle>Polym. Sci. Ser. A</stitle><date>2011-08-01</date><risdate>2011</risdate><volume>53</volume><issue>8</issue><spage>691</spage><epage>697</epage><pages>691-697</pages><issn>0965-545X</issn><issn>1757-1820</issn><eissn>1555-6107</eissn><abstract>It is shown that the amphiphilic diblock copolymers poly(
N
-vinylpyrrolidone-2,2,3,3-tetrafluoropropyl methacrylate) can be prepared through the reaction of chain transfer to bis(pentafluorophenyl)germane during the polymerization of
N
-vinylpyrrolidone and the subsequent postpolymerization of isolated functional polymers in 2,2,3,3-tetrafluoropropyl methacrylate. The dilute-solution behavior and self-organizing ability of functional polymers based on poly(
N
-vinylpyrrolidone) containing end bis(pentafluorophenyl) groups and of amphiphilic diblock copolymers formed on their basis are studied via the methods of static and dynamic light scattering and viscometry. Surface properties at the interface of the films are estimated through the wetting technique.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S0965545X11080128</doi><tpages>7</tpages></addata></record> |
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| identifier | ISSN: 0965-545X |
| ispartof | Polymer science. Series A, Chemistry, physics, 2011-08, Vol.53 (8), p.691-697 |
| issn | 0965-545X 1757-1820 1555-6107 |
| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Chain transfer Chemistry Chemistry and Materials Science Copolymers Dynamic tests Dynamics Polymer Sciences Polymerization Structure and Properties Surface properties Synthesis Viscometry |
| title | Synthesis and self-organization of amphiphilic poly(N-vinylpyrrolidone-2,2,3,3-tetrafluoropropyl methacrylate) diblock copolymers in solution and bulk |
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