Chiral sensing for induced circularly polarized luminescence using an Eu(III)-containing polymer and D- or L-proline

Chiral sensing for induced circularly polarized luminescence using an Eu(III)-containing polymer and D- or L-proline

An Eu(III)-containing polymer can exhibit intense induced circularly polarized luminescence (CPL) in the presence of proline. In addition, the optical anisotropy factor (g(lum)) of the polymer for (5)D0 → (7)F1/(7)F2 transition was much higher than that of a single model molecule, which reveals the...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (51), p.5772-5774
Hauptverfasser: Song, Fengyan, Wei, Guo, Jiang, Xiaoxiang, Li, Fei, Zhu, Chengjian, Cheng, Yixiang
Format: Artikel
Sprache:eng
Schlagworte:
Circular Dichroism
Coordination Complexes - chemistry
Europium - chemistry
Polymers - chemistry
Proline - chemistry
Spectrometry, Fluorescence
Stereoisomerism
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container_end_page 5774
container_issue 51
container_start_page 5772
container_title Chemical communications (Cambridge, England)
container_volume 49
creator Song, Fengyan
Wei, Guo
Jiang, Xiaoxiang
Li, Fei
Zhu, Chengjian
Cheng, Yixiang
description An Eu(III)-containing polymer can exhibit intense induced circularly polarized luminescence (CPL) in the presence of proline. In addition, the optical anisotropy factor (g(lum)) of the polymer for (5)D0 → (7)F1/(7)F2 transition was much higher than that of a single model molecule, which reveals the amplification effect of CPL arising from the conjugated polymer structure.
doi_str_mv 10.1039/c3cc42323a
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source MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Circular Dichroism
Coordination Complexes - chemistry
Europium - chemistry
Polymers - chemistry
Proline - chemistry
Spectrometry, Fluorescence
Stereoisomerism
title Chiral sensing for induced circularly polarized luminescence using an Eu(III)-containing polymer and D- or L-proline
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