Hydrogeochemistry and statistical analysis applied to understand fluoride provenance in the Guarani Aquifer System, Southern Brazil
High fluoride concentrations (up to 11 mg/L) have been reported in the groundwater of the Guarani Aquifer System (Santa Maria Formation) in the central region of the state of Rio Grande do Sul, Southern Brazil. In this area, dental fluorosis is an endemic disease. This paper presents the geochemical...
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Veröffentlicht in: | Environmental geochemistry and health 2013-06, Vol.35 (3), p.391-403 |
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description | High fluoride concentrations (up to 11 mg/L) have been reported in the groundwater of the Guarani Aquifer System (Santa Maria Formation) in the central region of the state of Rio Grande do Sul, Southern Brazil. In this area, dental fluorosis is an endemic disease. This paper presents the geochemical data and the combination of statistical analysis (Principal components and cluster analyses) and geochemical modeling to achieve the hydrogeochemistry of the groundwater and discusses the possible fluoride origin. The groundwater from the Santa Maria Formation is comprised of four different geochemical groups. The first group corresponds to a sodium chloride groundwater which evolves to sodium bicarbonate, the second one, both containing fluoride anomalies. The third group is represented by calcium bicarbonate groundwater, and in the fourth, magnesium is the distinctive parameter. The statistical and geochemical analyses supported by isotopic measurements indicated that groundwater may have originated from mixtures of deeper aquifers and the fluoride concentrations could be derived from rock/water interactions (e.g., desorption from clay minerals). |
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In this area, dental fluorosis is an endemic disease. This paper presents the geochemical data and the combination of statistical analysis (Principal components and cluster analyses) and geochemical modeling to achieve the hydrogeochemistry of the groundwater and discusses the possible fluoride origin. The groundwater from the Santa Maria Formation is comprised of four different geochemical groups. The first group corresponds to a sodium chloride groundwater which evolves to sodium bicarbonate, the second one, both containing fluoride anomalies. The third group is represented by calcium bicarbonate groundwater, and in the fourth, magnesium is the distinctive parameter. The statistical and geochemical analyses supported by isotopic measurements indicated that groundwater may have originated from mixtures of deeper aquifers and the fluoride concentrations could be derived from rock/water interactions (e.g., desorption from clay minerals).</description><identifier>ISSN: 0269-4042</identifier><identifier>EISSN: 1573-2983</identifier><identifier>DOI: 10.1007/s10653-012-9502-y</identifier><identifier>PMID: 23149723</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Aquifer systems ; Aquifers ; Brazil ; Clay minerals ; Cluster Analysis ; Earth and Environmental Science ; Environment ; Environmental Chemistry ; Environmental Exposure - adverse effects ; Environmental Health ; Environmental Monitoring - methods ; Fluorides ; Fluorides - analysis ; Fluorides - isolation & purification ; Fluorosis, Dental - epidemiology ; Geochemistry ; Groundwater ; Groundwater - analysis ; Groundwater - chemistry ; Humans ; Hydrology ; Magnesium ; Original Paper ; Principal Component Analysis ; Principal components analysis ; Public Health ; Sodium chloride ; Soil Science & Conservation ; Statistical analysis ; Terrestrial Pollution</subject><ispartof>Environmental geochemistry and health, 2013-06, Vol.35 (3), p.391-403</ispartof><rights>Springer Science+Business Media Dordrecht 2012</rights><rights>Springer Science+Business Media Dordrecht 2013</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a428t-928e2217027415f26740ffd52086a8e0fb607ac2540c3211d3c5d8e8de394edc3</citedby><cites>FETCH-LOGICAL-a428t-928e2217027415f26740ffd52086a8e0fb607ac2540c3211d3c5d8e8de394edc3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10653-012-9502-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10653-012-9502-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23149723$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Marimon, Maria Paula C.</creatorcontrib><creatorcontrib>Roisenberg, Ari</creatorcontrib><creatorcontrib>Suhogusoff, Alexandra V.</creatorcontrib><creatorcontrib>Viero, Antonio Pedro</creatorcontrib><title>Hydrogeochemistry and statistical analysis applied to understand fluoride provenance in the Guarani Aquifer System, Southern Brazil</title><title>Environmental geochemistry and health</title><addtitle>Environ Geochem Health</addtitle><addtitle>Environ Geochem Health</addtitle><description>High fluoride concentrations (up to 11 mg/L) have been reported in the groundwater of the Guarani Aquifer System (Santa Maria Formation) in the central region of the state of Rio Grande do Sul, Southern Brazil. In this area, dental fluorosis is an endemic disease. This paper presents the geochemical data and the combination of statistical analysis (Principal components and cluster analyses) and geochemical modeling to achieve the hydrogeochemistry of the groundwater and discusses the possible fluoride origin. The groundwater from the Santa Maria Formation is comprised of four different geochemical groups. The first group corresponds to a sodium chloride groundwater which evolves to sodium bicarbonate, the second one, both containing fluoride anomalies. The third group is represented by calcium bicarbonate groundwater, and in the fourth, magnesium is the distinctive parameter. The statistical and geochemical analyses supported by isotopic measurements indicated that groundwater may have originated from mixtures of deeper aquifers and the fluoride concentrations could be derived from rock/water interactions (e.g., desorption from clay minerals).</description><subject>Aquifer systems</subject><subject>Aquifers</subject><subject>Brazil</subject><subject>Clay minerals</subject><subject>Cluster Analysis</subject><subject>Earth and Environmental Science</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Exposure - adverse effects</subject><subject>Environmental Health</subject><subject>Environmental Monitoring - methods</subject><subject>Fluorides</subject><subject>Fluorides - analysis</subject><subject>Fluorides - isolation & purification</subject><subject>Fluorosis, Dental - epidemiology</subject><subject>Geochemistry</subject><subject>Groundwater</subject><subject>Groundwater - analysis</subject><subject>Groundwater - chemistry</subject><subject>Humans</subject><subject>Hydrology</subject><subject>Magnesium</subject><subject>Original Paper</subject><subject>Principal Component Analysis</subject><subject>Principal components analysis</subject><subject>Public Health</subject><subject>Sodium chloride</subject><subject>Soil Science & Conservation</subject><subject>Statistical analysis</subject><subject>Terrestrial Pollution</subject><issn>0269-4042</issn><issn>1573-2983</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1kU9rFjEQh4Mo9rX6AbxIwIsHVyd_drM51qKtUPBQPYc0mW1T9k3eJhthvfrFTdkqIngKwzzzyyQPIS8ZvGMA6n1hMPSiA8Y73QPv1kdkx3olOq5H8ZjsgA-6kyD5EXlWyi0AaCXHp-SICya14mJHfp6vPqdrTO4G96EseaU2eloWu7QqODu32s5rCYXaw2EO6OmSaI0ec4MaOs015eCRHnL6jtFGhzREutwgPas22xjoyV0NE2Z6uZYF92_pZaqtnSP9kO2PMD8nTyY7F3zxcB6Tb58-fj097y6-nH0-PbnorOTj0mk-IudMAVeS9RMflIRp8j2HcbAjwnQ1gLKO9xKc4Ix54Xo_4uhRaIneiWPyZsttm95VLItpL3Y4zzZiqsUw0Q9aMC1lQ1__g96mmttHbJQCIQAaxTbK5VRKxskcctjbvBoG5t6Q2QyZZsjcGzJrm3n1kFyv9uj_TPxW0gC-AaW14jXmv67-b-ov7t6dvw</recordid><startdate>20130601</startdate><enddate>20130601</enddate><creator>Marimon, Maria Paula C.</creator><creator>Roisenberg, Ari</creator><creator>Suhogusoff, Alexandra V.</creator><creator>Viero, Antonio Pedro</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7ST</scope><scope>7UA</scope><scope>7X7</scope><scope>7XB</scope><scope>88E</scope><scope>88I</scope><scope>8AO</scope><scope>8C1</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>F1W</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>H97</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>L.G</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>PATMY</scope><scope>PCBAR</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>SOI</scope><scope>7QH</scope><scope>7SN</scope><scope>7T2</scope><scope>7U2</scope></search><sort><creationdate>20130601</creationdate><title>Hydrogeochemistry and statistical analysis applied to understand fluoride provenance in the Guarani Aquifer System, Southern Brazil</title><author>Marimon, Maria Paula C. ; Roisenberg, Ari ; Suhogusoff, Alexandra V. ; Viero, Antonio Pedro</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a428t-928e2217027415f26740ffd52086a8e0fb607ac2540c3211d3c5d8e8de394edc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Aquifer systems</topic><topic>Aquifers</topic><topic>Brazil</topic><topic>Clay minerals</topic><topic>Cluster Analysis</topic><topic>Earth and Environmental Science</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Exposure - 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In this area, dental fluorosis is an endemic disease. This paper presents the geochemical data and the combination of statistical analysis (Principal components and cluster analyses) and geochemical modeling to achieve the hydrogeochemistry of the groundwater and discusses the possible fluoride origin. The groundwater from the Santa Maria Formation is comprised of four different geochemical groups. The first group corresponds to a sodium chloride groundwater which evolves to sodium bicarbonate, the second one, both containing fluoride anomalies. The third group is represented by calcium bicarbonate groundwater, and in the fourth, magnesium is the distinctive parameter. The statistical and geochemical analyses supported by isotopic measurements indicated that groundwater may have originated from mixtures of deeper aquifers and the fluoride concentrations could be derived from rock/water interactions (e.g., desorption from clay minerals).</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><pmid>23149723</pmid><doi>10.1007/s10653-012-9502-y</doi><tpages>13</tpages></addata></record> |
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subjects | Aquifer systems Aquifers Brazil Clay minerals Cluster Analysis Earth and Environmental Science Environment Environmental Chemistry Environmental Exposure - adverse effects Environmental Health Environmental Monitoring - methods Fluorides Fluorides - analysis Fluorides - isolation & purification Fluorosis, Dental - epidemiology Geochemistry Groundwater Groundwater - analysis Groundwater - chemistry Humans Hydrology Magnesium Original Paper Principal Component Analysis Principal components analysis Public Health Sodium chloride Soil Science & Conservation Statistical analysis Terrestrial Pollution |
title | Hydrogeochemistry and statistical analysis applied to understand fluoride provenance in the Guarani Aquifer System, Southern Brazil |
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