Hydrogeochemistry and statistical analysis applied to understand fluoride provenance in the Guarani Aquifer System, Southern Brazil

High fluoride concentrations (up to 11 mg/L) have been reported in the groundwater of the Guarani Aquifer System (Santa Maria Formation) in the central region of the state of Rio Grande do Sul, Southern Brazil. In this area, dental fluorosis is an endemic disease. This paper presents the geochemical...

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Veröffentlicht in:Environmental geochemistry and health 2013-06, Vol.35 (3), p.391-403
Hauptverfasser: Marimon, Maria Paula C., Roisenberg, Ari, Suhogusoff, Alexandra V., Viero, Antonio Pedro
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Roisenberg, Ari
Suhogusoff, Alexandra V.
Viero, Antonio Pedro
description High fluoride concentrations (up to 11 mg/L) have been reported in the groundwater of the Guarani Aquifer System (Santa Maria Formation) in the central region of the state of Rio Grande do Sul, Southern Brazil. In this area, dental fluorosis is an endemic disease. This paper presents the geochemical data and the combination of statistical analysis (Principal components and cluster analyses) and geochemical modeling to achieve the hydrogeochemistry of the groundwater and discusses the possible fluoride origin. The groundwater from the Santa Maria Formation is comprised of four different geochemical groups. The first group corresponds to a sodium chloride groundwater which evolves to sodium bicarbonate, the second one, both containing fluoride anomalies. The third group is represented by calcium bicarbonate groundwater, and in the fourth, magnesium is the distinctive parameter. The statistical and geochemical analyses supported by isotopic measurements indicated that groundwater may have originated from mixtures of deeper aquifers and the fluoride concentrations could be derived from rock/water interactions (e.g., desorption from clay minerals).
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subjects Aquifer systems
Aquifers
Brazil
Clay minerals
Cluster Analysis
Earth and Environmental Science
Environment
Environmental Chemistry
Environmental Exposure - adverse effects
Environmental Health
Environmental Monitoring - methods
Fluorides
Fluorides - analysis
Fluorides - isolation & purification
Fluorosis, Dental - epidemiology
Geochemistry
Groundwater
Groundwater - analysis
Groundwater - chemistry
Humans
Hydrology
Magnesium
Original Paper
Principal Component Analysis
Principal components analysis
Public Health
Sodium chloride
Soil Science & Conservation
Statistical analysis
Terrestrial Pollution
title Hydrogeochemistry and statistical analysis applied to understand fluoride provenance in the Guarani Aquifer System, Southern Brazil
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