POP-Pincer Osmium-Polyhydrides: Head-to-Head (Z)‑Dimerization of Terminal Alkynes

A wide range of osmium-polyhydride complexes stabilized by the POP-pincer ligand xant­(P i Pr2)2 (9,9-dimethyl-4,5-bis­(diisopropylphosphino)­xanthene) have been synthesized through cis-OsCl2{κ-S-(DMSO)4} (1, DMSO = dimethyl sulfoxide). Treatment of toluene solutions of this adduct with the diphosph...

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Veröffentlicht in:	Inorganic chemistry 2013-05, Vol.52 (10), p.6199-6213
Hauptverfasser:	Alós, Joaquín, Bolaño, Tamara, Esteruelas, Miguel A, Oliván, Montserrat, Oñate, Enrique, Valencia, Marta
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes - chemistry Dimerization Ethers - chemistry Models, Molecular Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Osmium - chemistry Quantum Theory Stereoisomerism
Online-Zugang:	Volltext
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