Palladium complexes with stabilized germylene and stannylene ligands
The syntheses of novel Pd complexes with germylene and stannylene ligands are reported. [MeN(CH2CH2NC6F5)2Sn]4Pd (2) and [MeN(CH2CPh2O)(CH2CH2O)Ge]4Pd (8) were obtained by different methods including ligand substitution in (Ph3P)4Pd or by the reaction of the free corresponding germylene or stannylen...
Gespeichert in:
| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2013-06, Vol.42 (22), p.7901-7912 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 7912 |
|---|---|
| container_issue | 22 |
| container_start_page | 7901 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 42 |
| creator | Kireenko, Marina M Zaitsev, Kirill V Oprunenko, Yuri F Churakov, Andrei V Tafeenko, Viktor A Karlov, Sergey S Zaitseva, Galina S |
| description | The syntheses of novel Pd complexes with germylene and stannylene ligands are reported. [MeN(CH2CH2NC6F5)2Sn]4Pd (2) and [MeN(CH2CPh2O)(CH2CH2O)Ge]4Pd (8) were obtained by different methods including ligand substitution in (Ph3P)4Pd or by the reaction of the free corresponding germylene or stannylene with (Ph3P)2PdCl2 or Pd(OAc)2. Crystal structures of complexes 2, 8 were determined by single crystal X-ray diffraction analysis. The catalytic activity of complexes 2, 8 was examined in the Suzuki-Miyaura and Heck cross-coupling. |
| doi_str_mv | 10.1039/c3dt32867h |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1353039557</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1353039557</sourcerecordid><originalsourceid>FETCH-LOGICAL-c287t-18e692f1bc6a156db987bfb01ea936cee0eae46d15967e7696c8fdf8b76ea2a83</originalsourceid><addsrcrecordid>eNpFkMtKw0AUhgdRbK1ufADJUoToXDq3pdQrFHSh6zCXk3ZkktRMgtanN6W1rs7l_zhwPoTOCb4mmOkbx3zHqBJyeYDGZCplrimbHu57KkboJKUPjCnFnB6j0RBjTAgfo7tXE6Pxoa8y11SrCN-Qsq_QLbPUGRti-AGfLaCt1hFqyEztN0Fdb8cYFsMmnaKj0sQEZ7s6Qe8P92-zp3z-8vg8u53njirZ5USB0LQk1glDuPBWK2lLiwkYzYQDwGBgKjzhWkiQQgunSl8qKwUYahSboMvt3VXbfPaQuqIKycHwQA1NnwrCOBuEcC4H9GqLurZJqYWyWLWhMu26ILjYWCv-rQ3wxe5ubyvwe_RPE_sFj6RpOA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1353039557</pqid></control><display><type>article</type><title>Palladium complexes with stabilized germylene and stannylene ligands</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Kireenko, Marina M ; Zaitsev, Kirill V ; Oprunenko, Yuri F ; Churakov, Andrei V ; Tafeenko, Viktor A ; Karlov, Sergey S ; Zaitseva, Galina S</creator><creatorcontrib>Kireenko, Marina M ; Zaitsev, Kirill V ; Oprunenko, Yuri F ; Churakov, Andrei V ; Tafeenko, Viktor A ; Karlov, Sergey S ; Zaitseva, Galina S</creatorcontrib><description>The syntheses of novel Pd complexes with germylene and stannylene ligands are reported. [MeN(CH2CH2NC6F5)2Sn]4Pd (2) and [MeN(CH2CPh2O)(CH2CH2O)Ge]4Pd (8) were obtained by different methods including ligand substitution in (Ph3P)4Pd or by the reaction of the free corresponding germylene or stannylene with (Ph3P)2PdCl2 or Pd(OAc)2. Crystal structures of complexes 2, 8 were determined by single crystal X-ray diffraction analysis. The catalytic activity of complexes 2, 8 was examined in the Suzuki-Miyaura and Heck cross-coupling.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c3dt32867h</identifier><identifier>PMID: 23400115</identifier><language>eng</language><publisher>England</publisher><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2013-06, Vol.42 (22), p.7901-7912</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c287t-18e692f1bc6a156db987bfb01ea936cee0eae46d15967e7696c8fdf8b76ea2a83</citedby><cites>FETCH-LOGICAL-c287t-18e692f1bc6a156db987bfb01ea936cee0eae46d15967e7696c8fdf8b76ea2a83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23400115$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kireenko, Marina M</creatorcontrib><creatorcontrib>Zaitsev, Kirill V</creatorcontrib><creatorcontrib>Oprunenko, Yuri F</creatorcontrib><creatorcontrib>Churakov, Andrei V</creatorcontrib><creatorcontrib>Tafeenko, Viktor A</creatorcontrib><creatorcontrib>Karlov, Sergey S</creatorcontrib><creatorcontrib>Zaitseva, Galina S</creatorcontrib><title>Palladium complexes with stabilized germylene and stannylene ligands</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>The syntheses of novel Pd complexes with germylene and stannylene ligands are reported. [MeN(CH2CH2NC6F5)2Sn]4Pd (2) and [MeN(CH2CPh2O)(CH2CH2O)Ge]4Pd (8) were obtained by different methods including ligand substitution in (Ph3P)4Pd or by the reaction of the free corresponding germylene or stannylene with (Ph3P)2PdCl2 or Pd(OAc)2. Crystal structures of complexes 2, 8 were determined by single crystal X-ray diffraction analysis. The catalytic activity of complexes 2, 8 was examined in the Suzuki-Miyaura and Heck cross-coupling.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNpFkMtKw0AUhgdRbK1ufADJUoToXDq3pdQrFHSh6zCXk3ZkktRMgtanN6W1rs7l_zhwPoTOCb4mmOkbx3zHqBJyeYDGZCplrimbHu57KkboJKUPjCnFnB6j0RBjTAgfo7tXE6Pxoa8y11SrCN-Qsq_QLbPUGRti-AGfLaCt1hFqyEztN0Fdb8cYFsMmnaKj0sQEZ7s6Qe8P92-zp3z-8vg8u53njirZ5USB0LQk1glDuPBWK2lLiwkYzYQDwGBgKjzhWkiQQgunSl8qKwUYahSboMvt3VXbfPaQuqIKycHwQA1NnwrCOBuEcC4H9GqLurZJqYWyWLWhMu26ILjYWCv-rQ3wxe5ubyvwe_RPE_sFj6RpOA</recordid><startdate>20130614</startdate><enddate>20130614</enddate><creator>Kireenko, Marina M</creator><creator>Zaitsev, Kirill V</creator><creator>Oprunenko, Yuri F</creator><creator>Churakov, Andrei V</creator><creator>Tafeenko, Viktor A</creator><creator>Karlov, Sergey S</creator><creator>Zaitseva, Galina S</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20130614</creationdate><title>Palladium complexes with stabilized germylene and stannylene ligands</title><author>Kireenko, Marina M ; Zaitsev, Kirill V ; Oprunenko, Yuri F ; Churakov, Andrei V ; Tafeenko, Viktor A ; Karlov, Sergey S ; Zaitseva, Galina S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c287t-18e692f1bc6a156db987bfb01ea936cee0eae46d15967e7696c8fdf8b76ea2a83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kireenko, Marina M</creatorcontrib><creatorcontrib>Zaitsev, Kirill V</creatorcontrib><creatorcontrib>Oprunenko, Yuri F</creatorcontrib><creatorcontrib>Churakov, Andrei V</creatorcontrib><creatorcontrib>Tafeenko, Viktor A</creatorcontrib><creatorcontrib>Karlov, Sergey S</creatorcontrib><creatorcontrib>Zaitseva, Galina S</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kireenko, Marina M</au><au>Zaitsev, Kirill V</au><au>Oprunenko, Yuri F</au><au>Churakov, Andrei V</au><au>Tafeenko, Viktor A</au><au>Karlov, Sergey S</au><au>Zaitseva, Galina S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Palladium complexes with stabilized germylene and stannylene ligands</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2013-06-14</date><risdate>2013</risdate><volume>42</volume><issue>22</issue><spage>7901</spage><epage>7912</epage><pages>7901-7912</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>The syntheses of novel Pd complexes with germylene and stannylene ligands are reported. [MeN(CH2CH2NC6F5)2Sn]4Pd (2) and [MeN(CH2CPh2O)(CH2CH2O)Ge]4Pd (8) were obtained by different methods including ligand substitution in (Ph3P)4Pd or by the reaction of the free corresponding germylene or stannylene with (Ph3P)2PdCl2 or Pd(OAc)2. Crystal structures of complexes 2, 8 were determined by single crystal X-ray diffraction analysis. The catalytic activity of complexes 2, 8 was examined in the Suzuki-Miyaura and Heck cross-coupling.</abstract><cop>England</cop><pmid>23400115</pmid><doi>10.1039/c3dt32867h</doi><tpages>12</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2013-06, Vol.42 (22), p.7901-7912 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1353039557 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Palladium complexes with stabilized germylene and stannylene ligands |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-16T06%3A56%3A56IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Palladium%20complexes%20with%20stabilized%20germylene%20and%20stannylene%20ligands&rft.jtitle=Dalton%20transactions%20:%20an%20international%20journal%20of%20inorganic%20chemistry&rft.au=Kireenko,%20Marina%20M&rft.date=2013-06-14&rft.volume=42&rft.issue=22&rft.spage=7901&rft.epage=7912&rft.pages=7901-7912&rft.issn=1477-9226&rft.eissn=1477-9234&rft_id=info:doi/10.1039/c3dt32867h&rft_dat=%3Cproquest_cross%3E1353039557%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1353039557&rft_id=info:pmid/23400115&rfr_iscdi=true |