Esterification of acrylic acid with 2-ethylhexan-1-ol: Thermodynamic and kinetic study
The activity and selectivity of polystyrene sulfonic acid resins (Amberlyst 39, Amberlyst 46, Amberlyst 70, and Amberlyst 131) were measured in the reaction of 2-ethylhexyl acrylate formation. The kinetics of the esterification of acrylic acid with 2-ethylhexan-1-ol was studied using Amberlyst 70 io...
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| Veröffentlicht in: | Applied catalysis. A, General General, 2013-01, Vol.451, p.127-136 |
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| container_title | Applied catalysis. A, General |
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| creator | KOMON, Tomasz NIEWIADOMSKI, Piotr ORACZ, Paweł JAMROZ, Małgorzata E |
| description | The activity and selectivity of polystyrene sulfonic acid resins (Amberlyst 39, Amberlyst 46, Amberlyst 70, and Amberlyst 131) were measured in the reaction of 2-ethylhexyl acrylate formation. The kinetics of the esterification of acrylic acid with 2-ethylhexan-1-ol was studied using Amberlyst 70 ion exchange resin (1a10 wt%) as a catalyst superior over a group of commercial catalysts. The 7: 1, 5: 1, 3: 1, 1: 1, 1: 3, 1: 5, and 1: 7 alcohol to acid molar ratio was used to carry out the reaction in an isothermal batch reactor at temperatures from 353 to 393 K. The studied mixtures are highly non-ideal, therefore, the kinetic equations and equilibrium parameters were expressed in terms of activities. |
| doi_str_mv | 10.1016/j.apcata.2012.11.018 |
| format | Article |
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The kinetics of the esterification of acrylic acid with 2-ethylhexan-1-ol was studied using Amberlyst 70 ion exchange resin (1a10 wt%) as a catalyst superior over a group of commercial catalysts. The 7: 1, 5: 1, 3: 1, 1: 1, 1: 3, 1: 5, and 1: 7 alcohol to acid molar ratio was used to carry out the reaction in an isothermal batch reactor at temperatures from 353 to 393 K. The studied mixtures are highly non-ideal, therefore, the kinetic equations and equilibrium parameters were expressed in terms of activities.</description><identifier>ISSN: 0926-860X</identifier><identifier>EISSN: 1873-3875</identifier><identifier>DOI: 10.1016/j.apcata.2012.11.018</identifier><language>eng</language><publisher>Kidlington: Elsevier</publisher><subject>Acrylic acid ; Catalysis ; Catalysts ; Chemistry ; Esterification ; Exact sciences and technology ; General and physical chemistry ; Ion exchange resins ; Polymers ; Reaction kinetics ; Reactors ; Sulfonic acid ; Theory of reactions, general kinetics. 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The studied mixtures are highly non-ideal, therefore, the kinetic equations and equilibrium parameters were expressed in terms of activities.</description><subject>Acrylic acid</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Esterification</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Ion exchange resins</subject><subject>Polymers</subject><subject>Reaction kinetics</subject><subject>Reactors</subject><subject>Sulfonic acid</subject><subject>Theory of reactions, general kinetics. Catalysis. 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| ispartof | Applied catalysis. A, General, 2013-01, Vol.451, p.127-136 |
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| source | Elsevier ScienceDirect Journals |
| subjects | Acrylic acid Catalysis Catalysts Chemistry Esterification Exact sciences and technology General and physical chemistry Ion exchange resins Polymers Reaction kinetics Reactors Sulfonic acid Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
| title | Esterification of acrylic acid with 2-ethylhexan-1-ol: Thermodynamic and kinetic study |
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