The fate of the fusarium mycotoxin zearalenone in maize cell suspension cultures

The fate of the fusarium mycotoxin zearalenone in maize cell suspension cultures

The fusarium mycotoxin zearalenone was transformed in cell suspension cultures of Zea mays giving α- and β-zearalenol and the β-D-glu cos ides of zearalenone and α- and β-zearalenol. The structure of zearalenone-4-β-D-glucopyranoside was determined by liquid - chromatography-mass spectrometry and sp...

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Veröffentlicht in:Mycotoxin research 1990-03, Vol.6 (1), p.31-40
Hauptverfasser: Zill, G, Engelhardt, G, Wohner, B, Wallnöfer, P
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creator Zill, G
Engelhardt, G
Wohner, B
Wallnöfer, P
description The fusarium mycotoxin zearalenone was transformed in cell suspension cultures of Zea mays giving α- and β-zearalenol and the β-D-glu cos ides of zearalenone and α- and β-zearalenol. The structure of zearalenone-4-β-D-glucopyranoside was determined by liquid - chromatography-mass spectrometry and specific hydrolysis with β-glucosidase. α- and β-zearalenol and their glucosides were identified by co chromatography using tic and HPLC and glucosidase - treatment Up to 50% of the mycotoxin added was bound to a non extractable or "bound" residue fraction. After treating this residue by a sequential cell wall fractionation procedure, zearalenone was found to be bound mainly to starch, hemicellulose, and lignin fractions.
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title The fate of the fusarium mycotoxin zearalenone in maize cell suspension cultures
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