The Formation of CuCl2-Specific Metallogels of Pyridyloxalamide Derivatives in Alcohols
Isomeric pyridyloxalamide derivatives 1–3, which differed in the position of the nitrogen atom on the pyridyl ring, showed remarkably different gel‐forming aptitudes in the presence of CuCl2 salt in alcohols. Whilst derivatives 1 and 3 formed a soluble complex and a solid precipitate, respectively,...
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| Veröffentlicht in: | Chemistry : a European journal 2013-04, Vol.19 (17), p.5411-5416 |
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| container_title | Chemistry : a European journal |
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| creator | Džolić, Zoran Cametti, Massimo Milić, Dalibor Žinić, Mladen |
| description | Isomeric pyridyloxalamide derivatives 1–3, which differed in the position of the nitrogen atom on the pyridyl ring, showed remarkably different gel‐forming aptitudes in the presence of CuCl2 salt in alcohols. Whilst derivatives 1 and 3 formed a soluble complex and a solid precipitate, respectively, ligand 2 generated a remarkably metal‐ and anion‐specific metallogel.
Fallen an‐gel: Isomeric pyridyloxalamide derivatives 1–3, which differed in the position of the nitrogen atom on the pyridyl ring, showed remarkably different gel‐forming aptitudes in the presence of CuCl2 salt in alcohols. Whilst derivatives 1 and 3 formed a soluble complex and a solid precipitate, respectively, ligand 2 generated a remarkably metal‐ and anion‐specific metallogel (see figure). |
| doi_str_mv | 10.1002/chem.201204082 |
| format | Article |
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Fallen an‐gel: Isomeric pyridyloxalamide derivatives 1–3, which differed in the position of the nitrogen atom on the pyridyl ring, showed remarkably different gel‐forming aptitudes in the presence of CuCl2 salt in alcohols. Whilst derivatives 1 and 3 formed a soluble complex and a solid precipitate, respectively, ligand 2 generated a remarkably metal‐ and anion‐specific metallogel (see figure).</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201204082</identifier><identifier>PMID: 23447553</identifier><identifier>CODEN: CEUJED</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>amino acids ; Chemistry ; copper ; gels ; oxalamides ; supramolecular chemistry</subject><ispartof>Chemistry : a European journal, 2013-04, Vol.19 (17), p.5411-5416</ispartof><rights>Copyright © 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201204082$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201204082$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23447553$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Džolić, Zoran</creatorcontrib><creatorcontrib>Cametti, Massimo</creatorcontrib><creatorcontrib>Milić, Dalibor</creatorcontrib><creatorcontrib>Žinić, Mladen</creatorcontrib><title>The Formation of CuCl2-Specific Metallogels of Pyridyloxalamide Derivatives in Alcohols</title><title>Chemistry : a European journal</title><addtitle>Chem. Eur. J</addtitle><description>Isomeric pyridyloxalamide derivatives 1–3, which differed in the position of the nitrogen atom on the pyridyl ring, showed remarkably different gel‐forming aptitudes in the presence of CuCl2 salt in alcohols. Whilst derivatives 1 and 3 formed a soluble complex and a solid precipitate, respectively, ligand 2 generated a remarkably metal‐ and anion‐specific metallogel.
Fallen an‐gel: Isomeric pyridyloxalamide derivatives 1–3, which differed in the position of the nitrogen atom on the pyridyl ring, showed remarkably different gel‐forming aptitudes in the presence of CuCl2 salt in alcohols. Whilst derivatives 1 and 3 formed a soluble complex and a solid precipitate, respectively, ligand 2 generated a remarkably metal‐ and anion‐specific metallogel (see figure).</description><subject>amino acids</subject><subject>Chemistry</subject><subject>copper</subject><subject>gels</subject><subject>oxalamides</subject><subject>supramolecular chemistry</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNpdkUFv2zAMRoVhw5q1u-44GNhlF3eSKFnWsXDbZFi7FW2KHAVZpht1cpRacdf8-zlIl8NOBMH3CIIfIZ8YPWWU8m9uid0pp4xTQUv-hkyY5CwHVci3ZEK1UHkhQR-RDyk9Ukp1AfCeHHEQQkkJE7KYLzG7jH1nNz6usthm1VAFnt-t0fnWu-waNzaE-IAh7aY329432xBfbLCdbzA7x94_j_IzpsyvsrPg4jKGdELetTYk_Phaj8n95cW8muVXv6bfq7Or_AEKwfO2KFmhoeWCqlYxhkIIaJhl0rZa17UABU40RUnLRnCuGxB16cA6jgiuqeGYfN3vXffxacC0MZ1PDkOwK4xDMgy4UlyUUo_ol__Qxzj0q_G6HVVwpqiSI_X5lRrqDhuz7n1n-63597IR0Hvgjw-4PcwZNbtAzC4QcwjEVLOL60M3uvne9WmDLwfX9r9NoUBJs_g5NfMf09ni9vzGTOEvXdKMmQ</recordid><startdate>20130422</startdate><enddate>20130422</enddate><creator>Džolić, Zoran</creator><creator>Cametti, Massimo</creator><creator>Milić, Dalibor</creator><creator>Žinić, Mladen</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope></search><sort><creationdate>20130422</creationdate><title>The Formation of CuCl2-Specific Metallogels of Pyridyloxalamide Derivatives in Alcohols</title><author>Džolić, Zoran ; Cametti, Massimo ; Milić, Dalibor ; Žinić, Mladen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-g3642-f681693f2407f711e4443d1a15af99bb4373c4d6808d4229d34b8c3ac2ee3cdb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>amino acids</topic><topic>Chemistry</topic><topic>copper</topic><topic>gels</topic><topic>oxalamides</topic><topic>supramolecular chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Džolić, Zoran</creatorcontrib><creatorcontrib>Cametti, Massimo</creatorcontrib><creatorcontrib>Milić, Dalibor</creatorcontrib><creatorcontrib>Žinić, Mladen</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Džolić, Zoran</au><au>Cametti, Massimo</au><au>Milić, Dalibor</au><au>Žinić, Mladen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Formation of CuCl2-Specific Metallogels of Pyridyloxalamide Derivatives in Alcohols</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chem. Eur. J</addtitle><date>2013-04-22</date><risdate>2013</risdate><volume>19</volume><issue>17</issue><spage>5411</spage><epage>5416</epage><pages>5411-5416</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><coden>CEUJED</coden><abstract>Isomeric pyridyloxalamide derivatives 1–3, which differed in the position of the nitrogen atom on the pyridyl ring, showed remarkably different gel‐forming aptitudes in the presence of CuCl2 salt in alcohols. Whilst derivatives 1 and 3 formed a soluble complex and a solid precipitate, respectively, ligand 2 generated a remarkably metal‐ and anion‐specific metallogel.
Fallen an‐gel: Isomeric pyridyloxalamide derivatives 1–3, which differed in the position of the nitrogen atom on the pyridyl ring, showed remarkably different gel‐forming aptitudes in the presence of CuCl2 salt in alcohols. Whilst derivatives 1 and 3 formed a soluble complex and a solid precipitate, respectively, ligand 2 generated a remarkably metal‐ and anion‐specific metallogel (see figure).</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>23447553</pmid><doi>10.1002/chem.201204082</doi><tpages>6</tpages></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | amino acids Chemistry copper gels oxalamides supramolecular chemistry |
| title | The Formation of CuCl2-Specific Metallogels of Pyridyloxalamide Derivatives in Alcohols |
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