Double Helices of a Pyridine-Appended Zinc Chlorophyll Derivative
Self-assembled structures formed from a pyridine-appended zinc chlorophyll derivative are reported. While the zinc complex forms cyclic oligomers in chloroform solution, as indicated by 1H NMR studies (including diffusion-ordered spectroscopy), vapor pressure osmometry, and cold-spray ionization mas...
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| Veröffentlicht in: | Journal of the American Chemical Society 2013-04, Vol.135 (14), p.5262-5265 |
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| container_end_page | 5265 |
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| container_issue | 14 |
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| container_title | Journal of the American Chemical Society |
| container_volume | 135 |
| creator | Shinozaki, Yoshinao Richards, Gary Ogawa, Keizo Yamano, Akihito Ohara, Kazuaki Yamaguchi, Kentaro Kawano, Shin-ichiro Tanaka, Kentaro Araki, Yasuyuki Wada, Takehiko Otsuki, Joe |
| description | Self-assembled structures formed from a pyridine-appended zinc chlorophyll derivative are reported. While the zinc complex forms cyclic oligomers in chloroform solution, as indicated by 1H NMR studies (including diffusion-ordered spectroscopy), vapor pressure osmometry, and cold-spray ionization mass spectrometry, it forms double-stranded helical coordination polymers in the solid state, as revealed by single-crystal X-ray analysis. |
| doi_str_mv | 10.1021/ja400493e |
| format | Article |
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Am. Chem. Soc</addtitle><description>Self-assembled structures formed from a pyridine-appended zinc chlorophyll derivative are reported. While the zinc complex forms cyclic oligomers in chloroform solution, as indicated by 1H NMR studies (including diffusion-ordered spectroscopy), vapor pressure osmometry, and cold-spray ionization mass spectrometry, it forms double-stranded helical coordination polymers in the solid state, as revealed by single-crystal X-ray analysis.</description><subject>Chlorophyll - chemistry</subject><subject>Coordination Complexes - chemical synthesis</subject><subject>Coordination Complexes - chemistry</subject><subject>Models, Molecular</subject><subject>Molecular Structure</subject><subject>Pyridines - chemistry</subject><subject>Zinc - chemistry</subject><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNptkM1KAzEURoMotlYXvoDMRtDFaP7TWZZWrVDQhW7cDJnkDk1JJ2PSKfTtHWntytXlwuHAdxC6JviBYEoeV5pjzAsGJ2hIBMW5IFSeoiHGmOZqLNkAXaS06l9Ox-QcDSgTlGBOhmgyC13lIZuDdwZSFupMZ--76KxrIJ-0LTQWbPblGpNNlz7E0C533mcziG6rN24Ll-is1j7B1eGO0Ofz08d0ni_eXl6nk0WuGRGbXBmtAFsmKypIYQpmqoKKSmKNbV0LqKStrZRYCaFqwYUtpKw05gKoUlJhNkJ3e28bw3cHaVOuXTLgvW4gdKkkjErCKeOsR-_3qIkhpQh12Ua31nFXElz-FiuPxXr25qDtqjXYI_mXqAdu94A2qVyFLjb9yn9EP6fpcEs</recordid><startdate>20130410</startdate><enddate>20130410</enddate><creator>Shinozaki, Yoshinao</creator><creator>Richards, Gary</creator><creator>Ogawa, Keizo</creator><creator>Yamano, Akihito</creator><creator>Ohara, Kazuaki</creator><creator>Yamaguchi, Kentaro</creator><creator>Kawano, Shin-ichiro</creator><creator>Tanaka, Kentaro</creator><creator>Araki, Yasuyuki</creator><creator>Wada, Takehiko</creator><creator>Otsuki, Joe</creator><general>American Chemical Society</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20130410</creationdate><title>Double Helices of a Pyridine-Appended Zinc Chlorophyll Derivative</title><author>Shinozaki, Yoshinao ; Richards, Gary ; Ogawa, Keizo ; Yamano, Akihito ; Ohara, Kazuaki ; Yamaguchi, Kentaro ; Kawano, Shin-ichiro ; Tanaka, Kentaro ; Araki, Yasuyuki ; Wada, Takehiko ; Otsuki, Joe</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a315t-7ca7e0d36b2519c93cb925b60a0dff5eb6dfd6607557f545d966ba045e2776703</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Chlorophyll - chemistry</topic><topic>Coordination Complexes - chemical synthesis</topic><topic>Coordination Complexes - chemistry</topic><topic>Models, Molecular</topic><topic>Molecular Structure</topic><topic>Pyridines - chemistry</topic><topic>Zinc - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shinozaki, Yoshinao</creatorcontrib><creatorcontrib>Richards, Gary</creatorcontrib><creatorcontrib>Ogawa, Keizo</creatorcontrib><creatorcontrib>Yamano, Akihito</creatorcontrib><creatorcontrib>Ohara, Kazuaki</creatorcontrib><creatorcontrib>Yamaguchi, Kentaro</creatorcontrib><creatorcontrib>Kawano, Shin-ichiro</creatorcontrib><creatorcontrib>Tanaka, Kentaro</creatorcontrib><creatorcontrib>Araki, Yasuyuki</creatorcontrib><creatorcontrib>Wada, Takehiko</creatorcontrib><creatorcontrib>Otsuki, Joe</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shinozaki, Yoshinao</au><au>Richards, Gary</au><au>Ogawa, Keizo</au><au>Yamano, Akihito</au><au>Ohara, Kazuaki</au><au>Yamaguchi, Kentaro</au><au>Kawano, Shin-ichiro</au><au>Tanaka, Kentaro</au><au>Araki, Yasuyuki</au><au>Wada, Takehiko</au><au>Otsuki, Joe</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Double Helices of a Pyridine-Appended Zinc Chlorophyll Derivative</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. 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| source | ACS Publications; MEDLINE |
| subjects | Chlorophyll - chemistry Coordination Complexes - chemical synthesis Coordination Complexes - chemistry Models, Molecular Molecular Structure Pyridines - chemistry Zinc - chemistry |
| title | Double Helices of a Pyridine-Appended Zinc Chlorophyll Derivative |
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