Effects of Electronics, Aromaticity, and Solvent Polarity on the Rate of Azaquinone–Methide-Mediated Depolymerization of Aromatic Carbamate Oligomers

This paper uses physical-organic studies on well-defined oligomers to establish design principles for creating aromatic poly(carbamates) that depolymerize from head-to-tail in low dielectric constant environments when exposed to specific applied signals. We show that either increasing electron densi...

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Veröffentlicht in:	Journal of organic chemistry 2013-04, Vol.78 (7), p.3159-3169
Hauptverfasser:	Robbins, Jessica S, Schmid, Kyle M, Phillips, Scott T
Format:	Artikel
Sprache:	eng
Schlagworte:	Aza Compounds - chemistry Carbamates - chemical synthesis Carbamates - chemistry Electronics Indolequinones - chemistry Molecular Structure Polymerization Solvents - chemistry
Online-Zugang:	Volltext
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