The early events in the OH radical oxidation of dimethyl sulfide in water

The time-resolved Raman observation of a prototype of the hetero-atom three electron bonds (-X-OH) that often form on encounter of the OH radical with chemical species in water is reported. In spite of their wide chemical and biochemical importance, no experimental structural information exists, thu...

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Veröffentlicht in:	The Journal of chemical physics 2013-01, Vol.138 (4), p.044506-044506
Hauptverfasser:	Janik, Ireneusz, Tripathi, G N R
Format:	Artikel
Sprache:	eng
Schlagworte:	Biochemistry Chemical bonds Dimethyl Encounters Gas phases Hydroxyl Radical - chemistry Mathematical models Oxidation-Reduction Quantum Theory Radicals Spectrum Analysis, Raman Sulfides Sulfides - chemistry Water - chemistry
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creator	Janik, Ireneusz Tripathi, G N R
description	The time-resolved Raman observation of a prototype of the hetero-atom three electron bonds (-X-OH) that often form on encounter of the OH radical with chemical species in water is reported. In spite of their wide chemical and biochemical importance, no experimental structural information exists, thus far, on any such bond in solution or in the gas phase. The nature of the >S-O bond formed on the reaction of the OH radical with dimethyl sulfide in water, investigated in the present work, would necessitate a reexamination of the existing reaction mechanisms in related biological systems and development of the appropriate computational methods.
doi_str_mv	10.1063/1.4788664
format	Article
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subjects	Biochemistry Chemical bonds Dimethyl Encounters Gas phases Hydroxyl Radical - chemistry Mathematical models Oxidation-Reduction Quantum Theory Radicals Spectrum Analysis, Raman Sulfides Sulfides - chemistry Water - chemistry
title	The early events in the OH radical oxidation of dimethyl sulfide in water
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