Isolation and characterization of microcrystalline cellulose from oil palm biomass residue
► Microcrystalline cellulose (MCC) was successfully isolated from oil palm biomass. ► Isolated MCC contains cellulose I with 87% crystallinity. ► MCC from OPEFB-pulp is shown to have good thermal stability. ► Atomic force microscopy shows that isolated MCC shows regular spherical particles. In this...
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| Veröffentlicht in: | Carbohydrate polymers 2013-04, Vol.93 (2), p.628-634 |
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| creator | Mohamad Haafiz, M.K. Eichhorn, S.J. Hassan, Azman Jawaid, M. |
| description | ► Microcrystalline cellulose (MCC) was successfully isolated from oil palm biomass. ► Isolated MCC contains cellulose I with 87% crystallinity. ► MCC from OPEFB-pulp is shown to have good thermal stability. ► Atomic force microscopy shows that isolated MCC shows regular spherical particles.
In this work, we successfully isolated microcrystalline cellulose (MCC) from oil palm empty fruit bunch (OPEFB) fiber-total chlorine free (TCF) pulp using acid hydrolysis method. TCF pulp bleaching carried out using an oxygen–ozone–hydrogen peroxide bleaching sequence. Fourier transform infrared (FT-IR) spectroscopy indicates that acid hydrolysis does not affect the chemical structure of the cellulosic fragments. The morphology of the hydrolyzed MCC was investigated using scanning electron microscopy (SEM), showing a compact structure and a rough surface. Furthermore, atomic force microscopy (AFM) image of the surface indicates the presence of spherical features. X-ray diffraction (XRD) shows that the MCC produced is a cellulose-I polymorph, with 87% crystallinity. The MCC obtained from OPEFB-pulp is shown to have a good thermal stability. The potential for a range of applications such as green nano biocomposites reinforced with this form of MCC and pharmaceutical tableting material is discussed. |
| doi_str_mv | 10.1016/j.carbpol.2013.01.035 |
| format | Article |
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In this work, we successfully isolated microcrystalline cellulose (MCC) from oil palm empty fruit bunch (OPEFB) fiber-total chlorine free (TCF) pulp using acid hydrolysis method. TCF pulp bleaching carried out using an oxygen–ozone–hydrogen peroxide bleaching sequence. Fourier transform infrared (FT-IR) spectroscopy indicates that acid hydrolysis does not affect the chemical structure of the cellulosic fragments. The morphology of the hydrolyzed MCC was investigated using scanning electron microscopy (SEM), showing a compact structure and a rough surface. Furthermore, atomic force microscopy (AFM) image of the surface indicates the presence of spherical features. X-ray diffraction (XRD) shows that the MCC produced is a cellulose-I polymorph, with 87% crystallinity. The MCC obtained from OPEFB-pulp is shown to have a good thermal stability. The potential for a range of applications such as green nano biocomposites reinforced with this form of MCC and pharmaceutical tableting material is discussed.</description><identifier>ISSN: 0144-8617</identifier><identifier>EISSN: 1879-1344</identifier><identifier>DOI: 10.1016/j.carbpol.2013.01.035</identifier><identifier>PMID: 23499105</identifier><identifier>CODEN: CAPOD8</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>acid hydrolysis ; Agronomy. Soil science and plant productions ; Applied sciences ; Araceae - chemistry ; atomic force microscopy ; biocomposites ; Biological and medical sciences ; biomass ; bleaching ; Cellulose ; Cellulose - chemistry ; Cellulose - isolation & purification ; Cellulose - ultrastructure ; Cellulose and derivatives ; chlorine ; crystal structure ; Elaeis guineensis ; Exact sciences and technology ; Fourier transform infrared spectroscopy ; Fruit - chemistry ; Fundamental and applied biological sciences. Psychology ; General agronomy. Plant production ; Hydrolysis ; Microcrystalline cellulose ; Microscopy, Electron, Scanning ; Natural polymers ; Oil palm empty fruit bunch ; Palm Oil ; Physicochemistry of polymers ; Plant Oils - chemistry ; pulp ; Pulp bleaching ; scanning electron microscopy ; Spectroscopy, Fourier Transform Infrared ; Sulfuric Acids - chemistry ; Surface Properties ; Temperature ; thermal stability ; Thermogravimetry ; Use of agricultural and forest wastes. Biomass use, bioconversion ; X-Ray Diffraction</subject><ispartof>Carbohydrate polymers, 2013-04, Vol.93 (2), p.628-634</ispartof><rights>2013 Elsevier Ltd</rights><rights>2014 INIST-CNRS</rights><rights>Copyright © 2013 Elsevier Ltd. All rights reserved.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c532t-4cc039918db382802e875f2a9c1c4aaf9a1b74e5e01fda8ac7a6acd76f1a19cb3</citedby><cites>FETCH-LOGICAL-c532t-4cc039918db382802e875f2a9c1c4aaf9a1b74e5e01fda8ac7a6acd76f1a19cb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.carbpol.2013.01.035$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27125147$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23499105$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Mohamad Haafiz, M.K.</creatorcontrib><creatorcontrib>Eichhorn, S.J.</creatorcontrib><creatorcontrib>Hassan, Azman</creatorcontrib><creatorcontrib>Jawaid, M.</creatorcontrib><title>Isolation and characterization of microcrystalline cellulose from oil palm biomass residue</title><title>Carbohydrate polymers</title><addtitle>Carbohydr Polym</addtitle><description>► Microcrystalline cellulose (MCC) was successfully isolated from oil palm biomass. ► Isolated MCC contains cellulose I with 87% crystallinity. ► MCC from OPEFB-pulp is shown to have good thermal stability. ► Atomic force microscopy shows that isolated MCC shows regular spherical particles.
In this work, we successfully isolated microcrystalline cellulose (MCC) from oil palm empty fruit bunch (OPEFB) fiber-total chlorine free (TCF) pulp using acid hydrolysis method. TCF pulp bleaching carried out using an oxygen–ozone–hydrogen peroxide bleaching sequence. Fourier transform infrared (FT-IR) spectroscopy indicates that acid hydrolysis does not affect the chemical structure of the cellulosic fragments. The morphology of the hydrolyzed MCC was investigated using scanning electron microscopy (SEM), showing a compact structure and a rough surface. Furthermore, atomic force microscopy (AFM) image of the surface indicates the presence of spherical features. X-ray diffraction (XRD) shows that the MCC produced is a cellulose-I polymorph, with 87% crystallinity. The MCC obtained from OPEFB-pulp is shown to have a good thermal stability. The potential for a range of applications such as green nano biocomposites reinforced with this form of MCC and pharmaceutical tableting material is discussed.</description><subject>acid hydrolysis</subject><subject>Agronomy. Soil science and plant productions</subject><subject>Applied sciences</subject><subject>Araceae - chemistry</subject><subject>atomic force microscopy</subject><subject>biocomposites</subject><subject>Biological and medical sciences</subject><subject>biomass</subject><subject>bleaching</subject><subject>Cellulose</subject><subject>Cellulose - chemistry</subject><subject>Cellulose - isolation & purification</subject><subject>Cellulose - ultrastructure</subject><subject>Cellulose and derivatives</subject><subject>chlorine</subject><subject>crystal structure</subject><subject>Elaeis guineensis</subject><subject>Exact sciences and technology</subject><subject>Fourier transform infrared spectroscopy</subject><subject>Fruit - chemistry</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>General agronomy. Plant production</subject><subject>Hydrolysis</subject><subject>Microcrystalline cellulose</subject><subject>Microscopy, Electron, Scanning</subject><subject>Natural polymers</subject><subject>Oil palm empty fruit bunch</subject><subject>Palm Oil</subject><subject>Physicochemistry of polymers</subject><subject>Plant Oils - chemistry</subject><subject>pulp</subject><subject>Pulp bleaching</subject><subject>scanning electron microscopy</subject><subject>Spectroscopy, Fourier Transform Infrared</subject><subject>Sulfuric Acids - chemistry</subject><subject>Surface Properties</subject><subject>Temperature</subject><subject>thermal stability</subject><subject>Thermogravimetry</subject><subject>Use of agricultural and forest wastes. Biomass use, bioconversion</subject><subject>X-Ray Diffraction</subject><issn>0144-8617</issn><issn>1879-1344</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkU1v1DAQhi1ERZfCTwByQeKS4MmXkxOqKj4qVeoBeuFiTSZj8MqJFztBan89XmWBY30ZyXpm5vVjIV6BLEBC-35fEIbh4F1RSqgKCYWsmidiB53qc6jq-qnYSajrvGtBnYvnMe5lOi3IZ-K8rOq-B9nsxPfr6B0u1s8ZzmNGPzEgLRzsw3bpTTZZCp7CfVzQOTtzRuzc6nzkzAQ_Zd667IBuygbrJ4wxCxztuPILcWbQRX55qhfi7tPHb1df8pvbz9dXlzc5NVW55DWRrFKabhyqruxkyZ1qTIk9AdWIpkcYVM0NSzAjdkgKW6RRtQYQehqqC_Fum3sI_tfKcdGTjceMOLNfo4YKVNfIVrUJbTY0vSjGwEYfgp0w3GuQ-qhV7_VJqz5q1RJ00pr6Xp9WrMPE47-uvx4T8PYEYCR0JuBMNv7nFJQN1CpxbzbOoNf4IyTm7mva1KavacquPRIfNoKTst-Wg45keSYebWBa9OjtI2H_ABljo7I</recordid><startdate>20130402</startdate><enddate>20130402</enddate><creator>Mohamad Haafiz, M.K.</creator><creator>Eichhorn, S.J.</creator><creator>Hassan, Azman</creator><creator>Jawaid, M.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>FBQ</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20130402</creationdate><title>Isolation and characterization of microcrystalline cellulose from oil palm biomass residue</title><author>Mohamad Haafiz, M.K. ; Eichhorn, S.J. ; Hassan, Azman ; Jawaid, M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c532t-4cc039918db382802e875f2a9c1c4aaf9a1b74e5e01fda8ac7a6acd76f1a19cb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>acid hydrolysis</topic><topic>Agronomy. Soil science and plant productions</topic><topic>Applied sciences</topic><topic>Araceae - chemistry</topic><topic>atomic force microscopy</topic><topic>biocomposites</topic><topic>Biological and medical sciences</topic><topic>biomass</topic><topic>bleaching</topic><topic>Cellulose</topic><topic>Cellulose - chemistry</topic><topic>Cellulose - isolation & purification</topic><topic>Cellulose - ultrastructure</topic><topic>Cellulose and derivatives</topic><topic>chlorine</topic><topic>crystal structure</topic><topic>Elaeis guineensis</topic><topic>Exact sciences and technology</topic><topic>Fourier transform infrared spectroscopy</topic><topic>Fruit - chemistry</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>General agronomy. Plant production</topic><topic>Hydrolysis</topic><topic>Microcrystalline cellulose</topic><topic>Microscopy, Electron, Scanning</topic><topic>Natural polymers</topic><topic>Oil palm empty fruit bunch</topic><topic>Palm Oil</topic><topic>Physicochemistry of polymers</topic><topic>Plant Oils - chemistry</topic><topic>pulp</topic><topic>Pulp bleaching</topic><topic>scanning electron microscopy</topic><topic>Spectroscopy, Fourier Transform Infrared</topic><topic>Sulfuric Acids - chemistry</topic><topic>Surface Properties</topic><topic>Temperature</topic><topic>thermal stability</topic><topic>Thermogravimetry</topic><topic>Use of agricultural and forest wastes. Biomass use, bioconversion</topic><topic>X-Ray Diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mohamad Haafiz, M.K.</creatorcontrib><creatorcontrib>Eichhorn, S.J.</creatorcontrib><creatorcontrib>Hassan, Azman</creatorcontrib><creatorcontrib>Jawaid, M.</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Carbohydrate polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mohamad Haafiz, M.K.</au><au>Eichhorn, S.J.</au><au>Hassan, Azman</au><au>Jawaid, M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Isolation and characterization of microcrystalline cellulose from oil palm biomass residue</atitle><jtitle>Carbohydrate polymers</jtitle><addtitle>Carbohydr Polym</addtitle><date>2013-04-02</date><risdate>2013</risdate><volume>93</volume><issue>2</issue><spage>628</spage><epage>634</epage><pages>628-634</pages><issn>0144-8617</issn><eissn>1879-1344</eissn><coden>CAPOD8</coden><abstract>► Microcrystalline cellulose (MCC) was successfully isolated from oil palm biomass. ► Isolated MCC contains cellulose I with 87% crystallinity. ► MCC from OPEFB-pulp is shown to have good thermal stability. ► Atomic force microscopy shows that isolated MCC shows regular spherical particles.
In this work, we successfully isolated microcrystalline cellulose (MCC) from oil palm empty fruit bunch (OPEFB) fiber-total chlorine free (TCF) pulp using acid hydrolysis method. TCF pulp bleaching carried out using an oxygen–ozone–hydrogen peroxide bleaching sequence. Fourier transform infrared (FT-IR) spectroscopy indicates that acid hydrolysis does not affect the chemical structure of the cellulosic fragments. The morphology of the hydrolyzed MCC was investigated using scanning electron microscopy (SEM), showing a compact structure and a rough surface. Furthermore, atomic force microscopy (AFM) image of the surface indicates the presence of spherical features. X-ray diffraction (XRD) shows that the MCC produced is a cellulose-I polymorph, with 87% crystallinity. The MCC obtained from OPEFB-pulp is shown to have a good thermal stability. The potential for a range of applications such as green nano biocomposites reinforced with this form of MCC and pharmaceutical tableting material is discussed.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><pmid>23499105</pmid><doi>10.1016/j.carbpol.2013.01.035</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | acid hydrolysis Agronomy. Soil science and plant productions Applied sciences Araceae - chemistry atomic force microscopy biocomposites Biological and medical sciences biomass bleaching Cellulose Cellulose - chemistry Cellulose - isolation & purification Cellulose - ultrastructure Cellulose and derivatives chlorine crystal structure Elaeis guineensis Exact sciences and technology Fourier transform infrared spectroscopy Fruit - chemistry Fundamental and applied biological sciences. Psychology General agronomy. Plant production Hydrolysis Microcrystalline cellulose Microscopy, Electron, Scanning Natural polymers Oil palm empty fruit bunch Palm Oil Physicochemistry of polymers Plant Oils - chemistry pulp Pulp bleaching scanning electron microscopy Spectroscopy, Fourier Transform Infrared Sulfuric Acids - chemistry Surface Properties Temperature thermal stability Thermogravimetry Use of agricultural and forest wastes. Biomass use, bioconversion X-Ray Diffraction |
| title | Isolation and characterization of microcrystalline cellulose from oil palm biomass residue |
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