Triarylsulfonium hexafluorophosphate salts as photoactivated acidic catalysts for ring-opening polymerisation

Triarylsulfonium hexafluorophosphate salts as photoactivated acidic catalysts for ring-opening polymerisation

Triarylsulfonium hexafluorophosphate salts were shown to be effective catalysts for the ring-opening polymerisation of various cyclic monomers under UV irradiation. A dual basic/acidic catalytic system demonstrated the potential for UV-triggered formation of poly(δ-valerolactone)-b-poly(L-lactide)-b...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (12), p.1205-1207
Hauptverfasser: Barker, Ian A, Dove, Andrew P
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Sprache:eng
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Catalysis
Catalysts
Irradiation
Monomers
Polymerization
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container_title Chemical communications (Cambridge, England)
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creator Barker, Ian A
Dove, Andrew P
description Triarylsulfonium hexafluorophosphate salts were shown to be effective catalysts for the ring-opening polymerisation of various cyclic monomers under UV irradiation. A dual basic/acidic catalytic system demonstrated the potential for UV-triggered formation of poly(δ-valerolactone)-b-poly(L-lactide)-b-poly(δ-valerolactone) in a 'one-pot' reaction.
doi_str_mv 10.1039/c2cc38114a
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source Royal Society Of Chemistry Journals; Alma/SFX Local Collection
subjects Catalysis
Catalysts
Irradiation
Monomers
Polymerization
title Triarylsulfonium hexafluorophosphate salts as photoactivated acidic catalysts for ring-opening polymerisation
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