Organic Single-Crystal Transistors Based on [pi]-Extended Heteroheptacene Microribbons

Facile synthesis of a new series of π-extended thienoacenes has been described. Their electronic structures have been elucidated by UV-vis absorption and photoelectron spectra. Well-defined single-crystal microribbons composed of self-organized thienoacene molecules have been fabricated using physic...

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Veröffentlicht in:	Bulletin of the Chemical Society of Japan 2012-11, Vol.85 (11), p.1186-1191
Hauptverfasser:	Seok Yang, Yu, Yasuda, Takuma, Adachi, Chihaya
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Sprache:	eng
Schlagworte:	Electronic structure Photoelectrons Semiconductor devices Single crystals Spectra Synthesis Transistors Transport
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creator	Seok Yang, Yu Yasuda, Takuma Adachi, Chihaya
description	Facile synthesis of a new series of π-extended thienoacenes has been described. Their electronic structures have been elucidated by UV-vis absorption and photoelectron spectra. Well-defined single-crystal microribbons composed of self-organized thienoacene molecules have been fabricated using physical vapor transport, and have been applied to field-effect transistors. The organic transistors employing the single-crystal microribbons exhibit mobilities as high as 0.47 cm2 V s-1 with on/off ratios of ca. 106.
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source	Oxford University Press Journals All Titles (1996-Current)
subjects	Electronic structure Photoelectrons Semiconductor devices Single crystals Spectra Synthesis Transistors Transport
title	Organic Single-Crystal Transistors Based on [pi]-Extended Heteroheptacene Microribbons
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