Carbon nanotube–metal oxide composite electrodes for secondary lithium-based batteries
Preparation and electrochemical evaluation of battery cathodes made from carbon nanotube substrates and lithium trivanadate (LiV3O8) are reported in this study. Our carbon nanotube substrate–LiV3O8 (CNT-SI) cathodes displayed good rate capability (>140 mAh/g on 1C discharge) and improved capacity...
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Veröffentlicht in: | Journal of composite materials 2013-01, Vol.47 (1), p.41-49 |
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creator | Marschilok, Amy C Schaffer, Corey P Takeuchi, Kenneth J Takeuchi, Esther S |
description | Preparation and electrochemical evaluation of battery cathodes made from carbon nanotube substrates and lithium trivanadate (LiV3O8) are reported in this study. Our carbon nanotube substrate–LiV3O8 (CNT-SI) cathodes displayed good rate capability (>140 mAh/g on 1C discharge) and improved capacity retention (>280 mAh/g after 30 cycles at C/20) when utilized in lithium-based batteries. The use of the CNT-SI composite where the electrodes are comprised of a carbon nanotube substrate and active material with no addition of binder, additional carbon additives, and without a foil backing provides the opportunity for a 25% increase in the percentage of active mass and a 36% reduction in the total electrode mass. These benefits demonstrate that considering electrode configuration as well as active material is a key strategic approach to enhance battery energy density. |
doi_str_mv | 10.1177/0021998312446827 |
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Our carbon nanotube substrate–LiV3O8 (CNT-SI) cathodes displayed good rate capability (>140 mAh/g on 1C discharge) and improved capacity retention (>280 mAh/g after 30 cycles at C/20) when utilized in lithium-based batteries. The use of the CNT-SI composite where the electrodes are comprised of a carbon nanotube substrate and active material with no addition of binder, additional carbon additives, and without a foil backing provides the opportunity for a 25% increase in the percentage of active mass and a 36% reduction in the total electrode mass. 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These benefits demonstrate that considering electrode configuration as well as active material is a key strategic approach to enhance battery energy density.</description><subject>Batteries</subject><subject>Carbon</subject><subject>Carbon nanotubes</subject><subject>Cathodes</subject><subject>Electric batteries</subject><subject>Electrodes</subject><subject>Nanocomposites</subject><subject>Nanostructure</subject><issn>0021-9983</issn><issn>1530-793X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp1kM1KxDAUhYMoOI7uXWbppnpv0jbtUgb_YMCNwuxK2txoh7apSQq68x18Q5_EDuNKcHUX5zsXvsPYOcIlolJXAALLspAo0jQvhDpgC8wkJKqUm0O22MXJLj9mJyFsAUBhmi_YZqV97QY-6MHFqabvz6-eou64e28N8cb1owttJE4dNdE7Q4Fb53mgxg1G-w_etfG1nfqk1oEMr3WM5FsKp-zI6i7Q2e9dsufbm6fVfbJ-vHtYXa-TRmYYE1vkWGsJpDUWUovC1jIVVqvMFIUqyyYHAjBGWjJlDlIoLVRmEVMxG9VWLtnF_u_o3dtEIVZ9GxrqOj2Qm0KFErM8zUHAjMIebbwLwZOtRt_2s0OFUO1GrP6OOFeSfSXoF6q2bvLDLPM__wN3ZXMm</recordid><startdate>201301</startdate><enddate>201301</enddate><creator>Marschilok, Amy C</creator><creator>Schaffer, Corey P</creator><creator>Takeuchi, Kenneth J</creator><creator>Takeuchi, Esther S</creator><general>SAGE Publications</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>201301</creationdate><title>Carbon nanotube–metal oxide composite electrodes for secondary lithium-based batteries</title><author>Marschilok, Amy C ; Schaffer, Corey P ; Takeuchi, Kenneth J ; Takeuchi, Esther S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c351t-f861ba30eaa183a28fb342fa75d88799c60e00dd3fed960327a275f1142021bf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Batteries</topic><topic>Carbon</topic><topic>Carbon nanotubes</topic><topic>Cathodes</topic><topic>Electric batteries</topic><topic>Electrodes</topic><topic>Nanocomposites</topic><topic>Nanostructure</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Marschilok, Amy C</creatorcontrib><creatorcontrib>Schaffer, Corey P</creatorcontrib><creatorcontrib>Takeuchi, Kenneth J</creatorcontrib><creatorcontrib>Takeuchi, Esther S</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of composite materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Marschilok, Amy C</au><au>Schaffer, Corey P</au><au>Takeuchi, Kenneth J</au><au>Takeuchi, Esther S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Carbon nanotube–metal oxide composite electrodes for secondary lithium-based batteries</atitle><jtitle>Journal of composite materials</jtitle><date>2013-01</date><risdate>2013</risdate><volume>47</volume><issue>1</issue><spage>41</spage><epage>49</epage><pages>41-49</pages><issn>0021-9983</issn><eissn>1530-793X</eissn><abstract>Preparation and electrochemical evaluation of battery cathodes made from carbon nanotube substrates and lithium trivanadate (LiV3O8) are reported in this study. 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subjects | Batteries Carbon Carbon nanotubes Cathodes Electric batteries Electrodes Nanocomposites Nanostructure |
title | Carbon nanotube–metal oxide composite electrodes for secondary lithium-based batteries |
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