Sequential Picosecond Isomerizations in a Photochromic Ruthenium Sulfoxide Complex Triggered by Pump-Repump-Probe Spectroscopy

The complex [Ru(bpy)2(bpSO)](PF6)2, where bpy is 2,2′-bipydine and bpSO is 1,2-bis(phenylsulfinyl)ethane, exhibits three distinct isomers which are accessible upon metal-to-ligand charge-transfer (MLCT) irradiation. This complex and its parent, [Ru(bpy)2(bpte)](PF6)2, where bpte is 1,2-bis(phenylthi...

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Veröffentlicht in:	Inorganic chemistry 2013-02, Vol.52 (4), p.2086-2093
Hauptverfasser:	King, Albert W, Jin, Yuhuan, Engle, James T, Ziegler, Christopher J, Rack, Jeffrey J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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