A new series of bis(ene-1,2-dithiolato)tungsten(IV), -(V), -(VI) complexes as reaction centre models of tungsten enzymes: preparation, crystal structures and spectroscopic properties

The carbomethoxy substituted dithiolene ligand (L(COOMe)) enabled us to develop a series of new bis(ene-1,2-dithiolato)tungsten complexes including W(IV)O, W(IV)(OSiBuPh(2)), W(VI)O(2), W(VI)O(OSiBuPh(2)) and W(VI)O(S) core structures. By using these tungsten complexes, a systematic study of the ter...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2013-03, Vol.42 (9), p.3059-3070
Hauptverfasser:	Sugimoto, Hideki, Hatakeda, Kohei, Toyota, Kazuo, Tatemoto, Susumu, Kubo, Minoru, Ogura, Takashi, Itoh, Shinobu
Format:	Artikel
Sprache:	eng
Schlagworte:	Biomimetic Materials - chemistry Crystallography, X-Ray Enzymes - chemistry Enzymes - metabolism Models, Molecular Molecular Conformation Organometallic Compounds - chemistry Spectrum Analysis Tungsten - chemistry
Online-Zugang:	Volltext
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