Combined Experimental and Theoretical Study on the Reductive Cleavage of Inert C–O Bonds with Silanes: Ruling out a Classical Ni(0)/Ni(II) Catalytic Couple and Evidence for Ni(I) Intermediates

A mechanistic and computational study on the reductive cleavage of C–OMe bonds catalyzed by Ni(COD)2/PCy3 with silanes as reducing agents is reported herein. Specifically, we demonstrate that the mechanism for this transformation does not proceed via oxidative addition of the Ni(0) precatalyst into...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of the American Chemical Society 2013-02, Vol.135 (5), p.1997-2009
Hauptverfasser:	Cornella, Josep, Gómez-Bengoa, Enrique, Martin, Ruben
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon - chemistry Catalysis Crystallography, X-Ray Ethers - chemistry Hydrocarbons, Aromatic - chemical synthesis Hydrocarbons, Aromatic - chemistry Models, Molecular Molecular Structure Nickel - chemistry Organometallic Compounds - chemistry Oxidation-Reduction Oxygen - chemistry Quantum Theory Silanes - chemistry
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!