Microscopic picture of aging in SiO2
We investigate the aging dynamics of amorphous SiO(2) via molecular dynamics simulations of a quench from a high temperature T(i) to a lower temperature T(f). We obtain a microscopic picture of aging dynamics by analyzing single particle trajectories, identifying jump events when a particle escapes...
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| Veröffentlicht in: | Physical review letters 2013-01, Vol.110 (1), p.017801-017801 |
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| container_title | Physical review letters |
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| creator | Vollmayr-Lee, Katharina Bjorkquist, Robin Chambers, Landon M |
| description | We investigate the aging dynamics of amorphous SiO(2) via molecular dynamics simulations of a quench from a high temperature T(i) to a lower temperature T(f). We obtain a microscopic picture of aging dynamics by analyzing single particle trajectories, identifying jump events when a particle escapes the cage formed by its neighbors, and determining how these jumps depend on the waiting time t(w), the time elapsed since the temperature quench to T(f). We find that the only t(w)-dependent microscopic quantity is the number of jumping particles per unit time, which decreases with age. Similar to previous studies for fragile glass formers, we show here for the strong glass former SiO(2) that neither the distribution of jump lengths nor the distribution of times spent in the cage are t(w) dependent. We conclude that the microscopic aging dynamics is surprisingly similar for fragile and strong glass formers. |
| doi_str_mv | 10.1103/PhysRevLett.110.017801 |
| format | Article |
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We obtain a microscopic picture of aging dynamics by analyzing single particle trajectories, identifying jump events when a particle escapes the cage formed by its neighbors, and determining how these jumps depend on the waiting time t(w), the time elapsed since the temperature quench to T(f). We find that the only t(w)-dependent microscopic quantity is the number of jumping particles per unit time, which decreases with age. Similar to previous studies for fragile glass formers, we show here for the strong glass former SiO(2) that neither the distribution of jump lengths nor the distribution of times spent in the cage are t(w) dependent. 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| fulltext | fulltext |
| identifier | EISSN: 1079-7114 |
| ispartof | Physical review letters, 2013-01, Vol.110 (1), p.017801-017801 |
| issn | 1079-7114 |
| language | eng |
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| source | MEDLINE; American Physical Society Journals |
| subjects | Microscopy - methods Models, Chemical Molecular Dynamics Simulation Silicon Dioxide - chemistry Temperature |
| title | Microscopic picture of aging in SiO2 |
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