A Super-Reduced Diferrous [2Fe–2S] Cluster

A biomimetic [2Fe–2S] cluster has been isolated in the fully reduced diferrous form and characterized by X-ray diffraction. This completes a consistent series of synthetic analogues of protein-bound [2Fe–2S] z redox centers (z = 2+, 1+, 0) with identical capping ligands. 57Fe Mössbauer data of the...

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Veröffentlicht in:	Journal of the American Chemical Society 2013-02, Vol.135 (5), p.1704-1707
Hauptverfasser:	Albers, Antonia, Demeshko, Serhiy, Pröpper, Kevin, Dechert, Sebastian, Bill, Eckhard, Meyer, Franc
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystallography, X-Ray Iron-Sulfur Proteins - chemistry Iron-Sulfur Proteins - isolation & purification Models, Molecular Molecular Structure Oxidation-Reduction Spectroscopy, Mossbauer
Online-Zugang:	Volltext
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