Hypervalent phenyl-[small lambda]3-iodane-mediated para-selective aromatic fluorination of 3-phenylpropyl ethers

Hypervalent phenyl-[small lambda]3-iodane-mediated para-selective aromatic fluorination of 3-phenylpropyl ethers

Exposure of 3-phenylpropyl ethers to an activated iodosylbenzene monomer[middle dot]18-crown-6 complex [PhI(OH)BF4[middle dot]18C6] in the presence of BF3-Et2O and water results in the para-selective monofluorination of benzene ring via neighboring alkoxy group participation and directly affords 3-(...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2011-01, Vol.47 (12), p.3410-3412
Hauptverfasser: Saito, Motomichi, Miyamoto, Kazunori, Ochiai, Masahito
Format: Artikel
Sprache:eng
Schlagworte:
Activated
Benzene
Ethers
Fluorination
Rings (mathematics)
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 3412
container_issue 12
container_start_page 3410
container_title Chemical communications (Cambridge, England)
container_volume 47
creator Saito, Motomichi
Miyamoto, Kazunori
Ochiai, Masahito
description Exposure of 3-phenylpropyl ethers to an activated iodosylbenzene monomer[middle dot]18-crown-6 complex [PhI(OH)BF4[middle dot]18C6] in the presence of BF3-Et2O and water results in the para-selective monofluorination of benzene ring via neighboring alkoxy group participation and directly affords 3-(4-fluorophenyl)propyl ethers regioselectively in good yields.
doi_str_mv 10.1039/C1CC10215J
format Article
fullrecord <record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_miscellaneous_1283701578</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1283701578</sourcerecordid><originalsourceid>FETCH-proquest_miscellaneous_12837015783</originalsourceid><addsrcrecordid>eNqVjs1OwzAQhH0AiZZy4Ql85OI2romSniOqinNvVVVtk41qtP7B61TK22MJXoC5zBw-zYwQr7pa68rsNp3uOl1tdf35IBba1DvVmPf6SSyZv6oiXbcLEQ9zxHQHQp9lvKGfSZ3YAZEkcNcBzkbZMIBH5XCwkHGQERIoRsI-2ztKSMFBtr0caQrJ-pKDl2GURv0WxhTiTBLzDROvxOMIxPjy58_ibf9x7A6qUN8Tcr44yz0Slckw8UVvW9OUr01r_oH-APCsU1Q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1283701578</pqid></control><display><type>article</type><title>Hypervalent phenyl-[small lambda]3-iodane-mediated para-selective aromatic fluorination of 3-phenylpropyl ethers</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Saito, Motomichi ; Miyamoto, Kazunori ; Ochiai, Masahito</creator><creatorcontrib>Saito, Motomichi ; Miyamoto, Kazunori ; Ochiai, Masahito</creatorcontrib><description>Exposure of 3-phenylpropyl ethers to an activated iodosylbenzene monomer[middle dot]18-crown-6 complex [PhI(OH)BF4[middle dot]18C6] in the presence of BF3-Et2O and water results in the para-selective monofluorination of benzene ring via neighboring alkoxy group participation and directly affords 3-(4-fluorophenyl)propyl ethers regioselectively in good yields.</description><identifier>ISSN: 1359-7345</identifier><identifier>DOI: 10.1039/C1CC10215J</identifier><language>eng</language><subject>Activated ; Benzene ; Ethers ; Fluorination ; Rings (mathematics)</subject><ispartof>Chemical communications (Cambridge, England), 2011-01, Vol.47 (12), p.3410-3412</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Saito, Motomichi</creatorcontrib><creatorcontrib>Miyamoto, Kazunori</creatorcontrib><creatorcontrib>Ochiai, Masahito</creatorcontrib><title>Hypervalent phenyl-[small lambda]3-iodane-mediated para-selective aromatic fluorination of 3-phenylpropyl ethers</title><title>Chemical communications (Cambridge, England)</title><description>Exposure of 3-phenylpropyl ethers to an activated iodosylbenzene monomer[middle dot]18-crown-6 complex [PhI(OH)BF4[middle dot]18C6] in the presence of BF3-Et2O and water results in the para-selective monofluorination of benzene ring via neighboring alkoxy group participation and directly affords 3-(4-fluorophenyl)propyl ethers regioselectively in good yields.</description><subject>Activated</subject><subject>Benzene</subject><subject>Ethers</subject><subject>Fluorination</subject><subject>Rings (mathematics)</subject><issn>1359-7345</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqVjs1OwzAQhH0AiZZy4Ql85OI2romSniOqinNvVVVtk41qtP7B61TK22MJXoC5zBw-zYwQr7pa68rsNp3uOl1tdf35IBba1DvVmPf6SSyZv6oiXbcLEQ9zxHQHQp9lvKGfSZ3YAZEkcNcBzkbZMIBH5XCwkHGQERIoRsI-2ztKSMFBtr0caQrJ-pKDl2GURv0WxhTiTBLzDROvxOMIxPjy58_ibf9x7A6qUN8Tcr44yz0Slckw8UVvW9OUr01r_oH-APCsU1Q</recordid><startdate>20110101</startdate><enddate>20110101</enddate><creator>Saito, Motomichi</creator><creator>Miyamoto, Kazunori</creator><creator>Ochiai, Masahito</creator><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20110101</creationdate><title>Hypervalent phenyl-[small lambda]3-iodane-mediated para-selective aromatic fluorination of 3-phenylpropyl ethers</title><author>Saito, Motomichi ; Miyamoto, Kazunori ; Ochiai, Masahito</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-proquest_miscellaneous_12837015783</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Activated</topic><topic>Benzene</topic><topic>Ethers</topic><topic>Fluorination</topic><topic>Rings (mathematics)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Saito, Motomichi</creatorcontrib><creatorcontrib>Miyamoto, Kazunori</creatorcontrib><creatorcontrib>Ochiai, Masahito</creatorcontrib><collection>Electronics &amp; Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Saito, Motomichi</au><au>Miyamoto, Kazunori</au><au>Ochiai, Masahito</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hypervalent phenyl-[small lambda]3-iodane-mediated para-selective aromatic fluorination of 3-phenylpropyl ethers</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2011-01-01</date><risdate>2011</risdate><volume>47</volume><issue>12</issue><spage>3410</spage><epage>3412</epage><pages>3410-3412</pages><issn>1359-7345</issn><abstract>Exposure of 3-phenylpropyl ethers to an activated iodosylbenzene monomer[middle dot]18-crown-6 complex [PhI(OH)BF4[middle dot]18C6] in the presence of BF3-Et2O and water results in the para-selective monofluorination of benzene ring via neighboring alkoxy group participation and directly affords 3-(4-fluorophenyl)propyl ethers regioselectively in good yields.</abstract><doi>10.1039/C1CC10215J</doi></addata></record>
fulltext fulltext
identifier ISSN: 1359-7345
ispartof Chemical communications (Cambridge, England), 2011-01, Vol.47 (12), p.3410-3412
issn 1359-7345
language eng
recordid cdi_proquest_miscellaneous_1283701578
source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Activated
Benzene
Ethers
Fluorination
Rings (mathematics)
title Hypervalent phenyl-[small lambda]3-iodane-mediated para-selective aromatic fluorination of 3-phenylpropyl ethers
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-28T10%3A36%3A27IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Hypervalent%20phenyl-%5Bsmall%20lambda%5D3-iodane-mediated%20para-selective%20aromatic%20fluorination%20of%203-phenylpropyl%20ethers&rft.jtitle=Chemical%20communications%20(Cambridge,%20England)&rft.au=Saito,%20Motomichi&rft.date=2011-01-01&rft.volume=47&rft.issue=12&rft.spage=3410&rft.epage=3412&rft.pages=3410-3412&rft.issn=1359-7345&rft_id=info:doi/10.1039/C1CC10215J&rft_dat=%3Cproquest%3E1283701578%3C/proquest%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1283701578&rft_id=info:pmid/&rfr_iscdi=true