Poly(glycidyl methacrylate): a highly versatile polymeric building block for post-polymerization modifications
The treatment of poly(glycidyl methacrylate) with nucleophilic agents yielded new linear homo/co-polymers. The materials obtained have different physicochemical properties depending upon the nucleophiles utilized and thus, by this way, water soluble polymers are easily accessible. This approach is a...
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Veröffentlicht in: | Polymer chemistry 2013-01, Vol.4 (1), p.124-132 |
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creator | Benaglia, Massimo Alberti, Angelo Giorgini, Loris Magnoni, Francesco Tozzi, Silvia |
description | The treatment of poly(glycidyl methacrylate) with nucleophilic agents yielded new linear homo/co-polymers. The materials obtained have different physicochemical properties depending upon the nucleophiles utilized and thus, by this way, water soluble polymers are easily accessible. This approach is also very convenient for the synthesis of amphiphilic block copolymers. Additional chemical modifications can further transform the obtained polymers after the post-polymerization treatment. Starting from RAFT pre-synthesized/pre-functionalized polymers, the described procedures allow us to obtain a wide variety of chemically diverse materials characterized by controlled structure and specific functions. |
doi_str_mv | 10.1039/C2PY20646C |
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The materials obtained have different physicochemical properties depending upon the nucleophiles utilized and thus, by this way, water soluble polymers are easily accessible. This approach is also very convenient for the synthesis of amphiphilic block copolymers. Additional chemical modifications can further transform the obtained polymers after the post-polymerization treatment. Starting from RAFT pre-synthesized/pre-functionalized polymers, the described procedures allow us to obtain a wide variety of chemically diverse materials characterized by controlled structure and specific functions.</description><subject>Block copolymers</subject><subject>Blocking</subject><subject>Copolymers</subject><subject>Nucleophiles</subject><subject>Rafts</subject><subject>Synthesis</subject><subject>Transforms</subject><subject>Water soluble polymers</subject><issn>1759-9954</issn><issn>1759-9962</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNpFkEtPwzAQhC0EElXphV_gY0EK-FUn5oYiCkiV6AEOnCLXWbcGJy52ihR-PYHymMvOaL_dwyB0SskFJVxdlmz5zIgUsjxAI5rPVKaUZId_fiaO0SSlFzKIU8G4HKF2GXw_XfveuLr3uIFuo03sve7g7AprvHHrje_xO8SkO-cBbwe-gegMXu2cr127xisfzCu2IQ7L1GW_xMdwEFrchNpZZ75DOkFHVvsEk585Rk_zm8fyLls83N6X14vMMCm6zFppRSFsbc2K81xyBjK3kkkDxFBacCEELUjBeMFyIFpwJqyEnILhM6lqPkbT_d9tDG87SF3VuGTAe91C2KWKsoLnhAqlBvR8j5oYUopgq210jY59RUn11Wv13yv_BK38bDY</recordid><startdate>20130101</startdate><enddate>20130101</enddate><creator>Benaglia, Massimo</creator><creator>Alberti, Angelo</creator><creator>Giorgini, Loris</creator><creator>Magnoni, Francesco</creator><creator>Tozzi, Silvia</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20130101</creationdate><title>Poly(glycidyl methacrylate): a highly versatile polymeric building block for post-polymerization modifications</title><author>Benaglia, Massimo ; Alberti, Angelo ; Giorgini, Loris ; Magnoni, Francesco ; Tozzi, Silvia</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c264t-ff6f484fdfcb337632e67f626ce0c1183444180823827e0a4324f6e71ec3569d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Block copolymers</topic><topic>Blocking</topic><topic>Copolymers</topic><topic>Nucleophiles</topic><topic>Rafts</topic><topic>Synthesis</topic><topic>Transforms</topic><topic>Water soluble polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Benaglia, Massimo</creatorcontrib><creatorcontrib>Alberti, Angelo</creatorcontrib><creatorcontrib>Giorgini, Loris</creatorcontrib><creatorcontrib>Magnoni, Francesco</creatorcontrib><creatorcontrib>Tozzi, Silvia</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Benaglia, Massimo</au><au>Alberti, Angelo</au><au>Giorgini, Loris</au><au>Magnoni, Francesco</au><au>Tozzi, Silvia</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Poly(glycidyl methacrylate): a highly versatile polymeric building block for post-polymerization modifications</atitle><jtitle>Polymer chemistry</jtitle><date>2013-01-01</date><risdate>2013</risdate><volume>4</volume><issue>1</issue><spage>124</spage><epage>132</epage><pages>124-132</pages><issn>1759-9954</issn><eissn>1759-9962</eissn><abstract>The treatment of poly(glycidyl methacrylate) with nucleophilic agents yielded new linear homo/co-polymers. 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subjects | Block copolymers Blocking Copolymers Nucleophiles Rafts Synthesis Transforms Water soluble polymers |
title | Poly(glycidyl methacrylate): a highly versatile polymeric building block for post-polymerization modifications |
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