Synthesis and characterization of new molecular imprinting poly[1-(N,N-bis-carboxymethyl)amino-3-allylglycerol-co-dimethylacrylamide] for selective sorption and determination of cefuroxime sodium in biological and pharmaceutical samples
Two molecular imprinting polymers (MIPs) based on solution and suspension polymerization were prepared with 1-(N,N-bis-carboxymethyl)amino-3-allylglycerol and N,N-dimethylacrylamide as functional monomers, and copper ion-cefuroxime sodium complex as the template. The imprinted polymers were characte...
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| Veröffentlicht in: | Reactive & functional polymers 2013-01, Vol.73 (1), p.132-140 |
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| creator | Panahi, Homayon Ahmad Mehramizi, Ali Hosseinifard, Zohrehsadat Moniri, Elham |
| description | Two molecular imprinting polymers (MIPs) based on solution and suspension polymerization were prepared with 1-(N,N-bis-carboxymethyl)amino-3-allylglycerol and N,N-dimethylacrylamide as functional monomers, and copper ion-cefuroxime sodium complex as the template. The imprinted polymers were characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, elemental analysis, Brunauer, Emmett and Teller method and scanning electron microscopy. The effects of the analytical parameters such as sample pH, contact time on sorption capacity of the polymeric sorbent and interfering drugs were investigated and compared for both polymers with different polymerization methods. The imprinted polymer sorbent was selective for the template. The profile of cefuroxime sodium uptake by the both sorbents reflects good accessibility of the active sites in the imprinted polymer sorbents. The equilibrium adsorption data of cefuroxime sodium on polymeric sorbents were analyzed by Langmuir, Freundlich, Temkin and Redlich–Peterson isotherm models. The developed method was utilized for determination of cefuroxime sodium in pharmaceutical and fluids biological samples like human plasma and urine by high performance liquid chromatography with satisfactory results. |
| doi_str_mv | 10.1016/j.reactfunctpolym.2012.08.021 |
| format | Article |
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The imprinted polymers were characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, elemental analysis, Brunauer, Emmett and Teller method and scanning electron microscopy. The effects of the analytical parameters such as sample pH, contact time on sorption capacity of the polymeric sorbent and interfering drugs were investigated and compared for both polymers with different polymerization methods. The imprinted polymer sorbent was selective for the template. The profile of cefuroxime sodium uptake by the both sorbents reflects good accessibility of the active sites in the imprinted polymer sorbents. The equilibrium adsorption data of cefuroxime sodium on polymeric sorbents were analyzed by Langmuir, Freundlich, Temkin and Redlich–Peterson isotherm models. The developed method was utilized for determination of cefuroxime sodium in pharmaceutical and fluids biological samples like human plasma and urine by high performance liquid chromatography with satisfactory results.</description><identifier>ISSN: 1381-5148</identifier><identifier>DOI: 10.1016/j.reactfunctpolym.2012.08.021</identifier><language>eng</language><publisher>Kidlington: Elsevier B.V</publisher><subject>Applied sciences ; Biological and medical sciences ; Biological fluids ; Cefuroxime sodium ; Exact sciences and technology ; General pharmacology ; Medical sciences ; Molecular imprinting polymer ; Organic polymers ; Pharmaceutical sample ; Pharmaceutical technology. Pharmaceutical industry ; Pharmacology. 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The imprinted polymers were characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, elemental analysis, Brunauer, Emmett and Teller method and scanning electron microscopy. The effects of the analytical parameters such as sample pH, contact time on sorption capacity of the polymeric sorbent and interfering drugs were investigated and compared for both polymers with different polymerization methods. The imprinted polymer sorbent was selective for the template. The profile of cefuroxime sodium uptake by the both sorbents reflects good accessibility of the active sites in the imprinted polymer sorbents. The equilibrium adsorption data of cefuroxime sodium on polymeric sorbents were analyzed by Langmuir, Freundlich, Temkin and Redlich–Peterson isotherm models. The developed method was utilized for determination of cefuroxime sodium in pharmaceutical and fluids biological samples like human plasma and urine by high performance liquid chromatography with satisfactory results.</description><subject>Applied sciences</subject><subject>Biological and medical sciences</subject><subject>Biological fluids</subject><subject>Cefuroxime sodium</subject><subject>Exact sciences and technology</subject><subject>General pharmacology</subject><subject>Medical sciences</subject><subject>Molecular imprinting polymer</subject><subject>Organic polymers</subject><subject>Pharmaceutical sample</subject><subject>Pharmaceutical technology. Pharmaceutical industry</subject><subject>Pharmacology. Drug treatments</subject><subject>Physicochemistry of polymers</subject><subject>Polymers with particular properties</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Solution and suspension polymerization</subject><issn>1381-5148</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqNUctu1DAUzQIkSuEfvKlUJDzYcSaJFyxQBQWpKgtghZB1x7me8ciPYCel4Zv5CDwzVRes2PhK1rnncU9VXXC24oy3b_arhKAnMwc9jdEtflUzXq9Yv2I1f1KdcdFzuuZN_6x6nvOeMd7xtj2r_nxZwrTDbDOBMBC9g1RoMNnfMNkYSDQk4C_io0M9O0jE-jHZMNmwJQed75xe3r6-pRubqYa0ifeLx2m3uFfgbYhUUHBucVu3aEzRUR3pYE8I0Kk83g74g5iYSMaiMdk7JDmm8ah-sDRgsVO4Hv1oNHOK94WlAAc7e2ID2djo4tZqcMelseTwoHGejl8Z_Ogwv6ieGnAZXz7M8-rbh_dfrz7Sm8_Xn67e3VAtZDtR2TXAetlsOrPpBF-DhrquG8Ratr1Zd5y1g5DQrLWRfb_mUugaEZquMUIOshHn1eWJd0zx54x5Ut5mjc5BwDhnxetetK2UnBfo2xNUp5hzQqPKeT2kRXGmDs2qvfqnWXVoVrFelWbL_sWDFOSS1CQI2uZHkrrtBWfiYOn6hMOS-85iUllbDBoHm8rV1RDtfyr-BRntzhU</recordid><startdate>201301</startdate><enddate>201301</enddate><creator>Panahi, Homayon Ahmad</creator><creator>Mehramizi, Ali</creator><creator>Hosseinifard, Zohrehsadat</creator><creator>Moniri, Elham</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>8FD</scope><scope>FR3</scope><scope>P64</scope></search><sort><creationdate>201301</creationdate><title>Synthesis and characterization of new molecular imprinting poly[1-(N,N-bis-carboxymethyl)amino-3-allylglycerol-co-dimethylacrylamide] for selective sorption and determination of cefuroxime sodium in biological and pharmaceutical samples</title><author>Panahi, Homayon Ahmad ; Mehramizi, Ali ; Hosseinifard, Zohrehsadat ; Moniri, Elham</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c396t-974a0894b7fb7315aca2224ee2968f57106d39a45cf9885193c2eea474f39d943</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Applied sciences</topic><topic>Biological and medical sciences</topic><topic>Biological fluids</topic><topic>Cefuroxime sodium</topic><topic>Exact sciences and technology</topic><topic>General pharmacology</topic><topic>Medical sciences</topic><topic>Molecular imprinting polymer</topic><topic>Organic polymers</topic><topic>Pharmaceutical sample</topic><topic>Pharmaceutical technology. Pharmaceutical industry</topic><topic>Pharmacology. Drug treatments</topic><topic>Physicochemistry of polymers</topic><topic>Polymers with particular properties</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Solution and suspension polymerization</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Panahi, Homayon Ahmad</creatorcontrib><creatorcontrib>Mehramizi, Ali</creatorcontrib><creatorcontrib>Hosseinifard, Zohrehsadat</creatorcontrib><creatorcontrib>Moniri, Elham</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Reactive & functional polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Panahi, Homayon Ahmad</au><au>Mehramizi, Ali</au><au>Hosseinifard, Zohrehsadat</au><au>Moniri, Elham</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and characterization of new molecular imprinting poly[1-(N,N-bis-carboxymethyl)amino-3-allylglycerol-co-dimethylacrylamide] for selective sorption and determination of cefuroxime sodium in biological and pharmaceutical samples</atitle><jtitle>Reactive & functional polymers</jtitle><date>2013-01</date><risdate>2013</risdate><volume>73</volume><issue>1</issue><spage>132</spage><epage>140</epage><pages>132-140</pages><issn>1381-5148</issn><abstract>Two molecular imprinting polymers (MIPs) based on solution and suspension polymerization were prepared with 1-(N,N-bis-carboxymethyl)amino-3-allylglycerol and N,N-dimethylacrylamide as functional monomers, and copper ion-cefuroxime sodium complex as the template. The imprinted polymers were characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, elemental analysis, Brunauer, Emmett and Teller method and scanning electron microscopy. The effects of the analytical parameters such as sample pH, contact time on sorption capacity of the polymeric sorbent and interfering drugs were investigated and compared for both polymers with different polymerization methods. The imprinted polymer sorbent was selective for the template. The profile of cefuroxime sodium uptake by the both sorbents reflects good accessibility of the active sites in the imprinted polymer sorbents. The equilibrium adsorption data of cefuroxime sodium on polymeric sorbents were analyzed by Langmuir, Freundlich, Temkin and Redlich–Peterson isotherm models. 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| subjects | Applied sciences Biological and medical sciences Biological fluids Cefuroxime sodium Exact sciences and technology General pharmacology Medical sciences Molecular imprinting polymer Organic polymers Pharmaceutical sample Pharmaceutical technology. Pharmaceutical industry Pharmacology. Drug treatments Physicochemistry of polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts Solution and suspension polymerization |
| title | Synthesis and characterization of new molecular imprinting poly[1-(N,N-bis-carboxymethyl)amino-3-allylglycerol-co-dimethylacrylamide] for selective sorption and determination of cefuroxime sodium in biological and pharmaceutical samples |
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