Strong Negative Synergism of Ion Pair Extinction Coefficients in ChloroformaAcetone and Methylene DichlorideaAcetone Mixtures

The heteroselective preferential solvation of the iodides of N-heterocyclic aromatic cations in acetoneachloroalkane (chloroform and dichloromethane) binary mixtures results in not only a shift in the maxima of outer-sphere charge transfer absorption bands but also a considerable decrease in the mol...

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Veröffentlicht in:	Mendeleev communications 2012-12, Vol.22 (6), p.320-322
Hauptverfasser:	Birin, Kirill P, Dunin, Dmitry S, Tolstykh, Maxim V, Kotov, Vitalii Yu
Format:	Artikel
Sprache:	eng
Schlagworte:	Cations Charge transfer Extinction Iodides Ion pairs Maxima Methylene Solvation
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description	The heteroselective preferential solvation of the iodides of N-heterocyclic aromatic cations in acetoneachloroalkane (chloroform and dichloromethane) binary mixtures results in not only a shift in the maxima of outer-sphere charge transfer absorption bands but also a considerable decrease in the molar extinction coefficients of ion pairs.
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subjects	Cations Charge transfer Extinction Iodides Ion pairs Maxima Methylene Solvation
title	Strong Negative Synergism of Ion Pair Extinction Coefficients in ChloroformaAcetone and Methylene DichlorideaAcetone Mixtures
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