Thermodynamic growth model of single crystal Bi-2212 whisker

► Whiskers growth is related by surface energy change. ► It was found that needle-like grain formation needs higher free energy. ► Evaporation of ions supports whisker formation. In this study the growth mechanism of superconducting Bi-2212 whiskers is investigated from a thermodynamic point of view...

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Veröffentlicht in:Physica. C, Superconductivity Superconductivity, 2012-12, Vol.483, p.140-143
Hauptverfasser: Altin, S., Yakinci, M.E.
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description ► Whiskers growth is related by surface energy change. ► It was found that needle-like grain formation needs higher free energy. ► Evaporation of ions supports whisker formation. In this study the growth mechanism of superconducting Bi-2212 whiskers is investigated from a thermodynamic point of view. The evolution of the free energy of the growth region in the main matrix is evaluated by estimating that of its surface energy. It is shown that the local free energy change for partial melting is the same as that of the whole structure of the sample. It is pointed out that the formation of whiskers requires a higher energy than that of plate like grains.
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subjects Bi-2212
Bi-based cuprates
Condensed matter: electronic structure, electrical, magnetic, and optical properties
COPPER OXIDE
Cross-disciplinary physics: materials science
rheology
Cuprates superconductors (high tc and insulating parent compounds)
Evolution
Exact sciences and technology
FREE ENERGY
FREE ENERGY OF FORMATION
Growth model
Materials science
MELTING
Methods of crystal growth
physics of crystal growth
Physics
Plates (structural members)
SINGLE CRYSTALS
SUPERCONDUCTIVITY
SUPERCONDUCTORS
SURFACE ENERGY
Theory and models of crystal growth
physics of crystal growth, crystal morphology and orientation
THERMODYNAMIC PROPERTIES
Thermodynamics
Whisker
title Thermodynamic growth model of single crystal Bi-2212 whisker
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