Oxidation and Reduction of Bis(imino)pyridine Iron Dinitrogen Complexes: Evidence for Formation of a Chelate Trianion

Oxidation and reduction of the bis(imino)pyridine iron dinitrogen compound, (iPrPDI)FeN2 (iPrPDI = 2,6-(2,6-iPr2–C6H3–NCMe)2C5H3N) has been examined to determine whether the redox events are metal or ligand based. Treatment of (iPrPDI)FeN2 with [Cp2Fe][BArF 4] (BArF 4 = B(3,5-(CF3)2-C6H3)4) in diet...

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Veröffentlicht in:	Inorganic chemistry 2013-01, Vol.52 (2), p.635-646
Hauptverfasser:	Tondreau, Aaron M, Stieber, S. Chantal E, Milsmann, Carsten, Lobkovsky, Emil, Weyhermüller, Thomas, Semproni, Scott P, Chirik, Paul J
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions Electrons Imines - chemistry Iron - chemistry Iron Chelating Agents - chemistry Molecular Structure Nitrogen - chemistry Oxidation-Reduction Pyridines - chemistry Quantum Theory Spectroscopy, Mossbauer
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