Metal-Ion Metathesis in Metal-Organic Frameworks: A Synthetic Route to New Metal-Organic Frameworks

A porous metal–organic framework, Mn(H3O)[(Mn4Cl)3(hmtt)8] (POST‐65), was prepared by the reaction of 5,5′,10,10′,15,15′‐hexamethyltruxene‐2,7,12‐tricarboxylic acid (H3hmtt) with MnCl2 under solvothermal conditions. POST‐65(Mn) was subjected to post‐synthetic modification with Fe, Co, Ni, and Cu acc...

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