Total Structure and Electronic Properties of the Gold Nanocrystal Au36(SR)24

A golden opportunity: The total structure of a Au36(SR)24 nanocluster (see figure) reveals an unexpected face‐centered‐cubic tetrahedral Au28 kernel (magenta). The protecting layer exhibits an intriguing combination of binding modes, consisting of four regular arch‐like staples and the unprecedented...

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Veröffentlicht in:	Angewandte Chemie International Edition 2012-12, Vol.51 (52), p.13114-13118
Hauptverfasser:	Zeng, Chenjie, Qian, Huifeng, Li, Tao, Li, Gao, Rosi, Nathaniel L., Yoon, Bokwon, Barnett, Robert N., Whetten, Robert L., Landman, Uzi, Jin, Rongchao
Format:	Artikel
Sprache:	eng
Schlagworte:	cluster compounds Crystallography, X-Ray Electrons face-centered cubic gold Gold - chemistry Metal Nanoparticles - chemistry Molecular Conformation nanostructures Quantum Theory tetrahedral structures
Online-Zugang:	Volltext
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