Direct α‑Functionalization of Simple Aldehydes via Oxidative N‑Heterocyclic Carbene Catalysis

A direct α-functionalization of simple aldehydes under N-Heterocyclic Carbene (NHC) catalysis and direct generation of ester enolate equivalents from nonfunctionalized aldehydes are disclosed. The catalysis involves selective enolate generation from an oxidatively generated NHC-bounded ester interme...

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Veröffentlicht in:	Organic letters 2013-01, Vol.15 (1), p.50-53
Hauptverfasser:	Mo, Junming, Yang, Ruojie, Chen, Xingkuan, Tiwari, Bhoopendra, Chi, Yonggui Robin
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes - chemistry Catalysis Heterocyclic Compounds - chemistry Ketones - chemistry Methane - analogs & derivatives Methane - chemistry Molecular Structure Oxidation-Reduction
Online-Zugang:	Volltext
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