Dibromido(6,6'-dimethyl-2,2'-bipyridine-κ(2)N,N')cobalt(II)

Dibromido(6,6'-dimethyl-2,2'-bipyridine-κ(2)N,N')cobalt(II)

In the title compound, [CoBr(2)(C(12)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 6,6'-dimethyl-2,2'-bipyridine ligand and by two terminal Br atoms. Inter-molecular C-H⋯Br hydrogen bonds and π-π stacking between the pyridine ri...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-11, Vol.68 (Pt 11), p.m1363-m1363
Hauptverfasser: Shirvan, Sadif A, Haydari Dezfuli, Sara, Khazali, Fereydoon, Aghajeri, Manouchehr, Borsalani, Ali
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container_issue Pt 11
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container_title Acta crystallographica. Section E, Structure reports online
container_volume 68
creator Shirvan, Sadif A
Haydari Dezfuli, Sara
Khazali, Fereydoon
Aghajeri, Manouchehr
Borsalani, Ali
description In the title compound, [CoBr(2)(C(12)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 6,6'-dimethyl-2,2'-bipyridine ligand and by two terminal Br atoms. Inter-molecular C-H⋯Br hydrogen bonds and π-π stacking between the pyridine rings in the bc plane [centroid-centroid distance = 3.725 (3) Å] are present in the crystal structure.
doi_str_mv 10.1107/S1600536812041980
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title Dibromido(6,6'-dimethyl-2,2'-bipyridine-κ(2)N,N')cobalt(II)
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